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单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,氯化橡胶涂料,在集装箱行业的应用,中远关西涂料 刘会成,集装箱涂料相关标准,3,集装箱行业介绍,1,氯化橡胶类涂料的缺陷及改进要求,4,集装箱涂装配套,2,Content,集装箱的诞生,雏形,创立,成长,成熟,1801,Dr.James Anderson,Word War II,Weapons Transportation,19561966,Aril 26th,1956,“Macedonia”,(Pan-Atlantic Steamship Co.),Oct.1957,“Gateway City”,19661980s,Construction of Container Terminal,“Door to Door”,International,Systematic,1980s,Containerization,more than 80%,Joint Venture Global Alliance,集装箱制造业转移,1970s Starting in USA,and soon transferred to Europe,中国,韩国,/,台湾,日本,欧美,1970s1980s,Japan took over the baton,1980s1990s,Korea was the main force in the container manufacturing,1990s,More than 95%of container were producted in China,集装箱在中国,April,1955,Short-term trial operation,1973,Maritime container trasport,Sept.1973,1st international container,1970s,起步,1980s,成长,1990s,发展,世界,集装箱运输和制造业焦点,2011,年全世界,10,个最大的集装箱港口中，有,6,个在中国,上海,(1),香港,(3),深圳,(4),宁波,(6),青岛,(7),广州,(8),中远,COSCO,中海,China Shipping,东方海外,OOCL(Hong Kong),长荣,Evergreen(Taiwan)a,，万海,Wan Hai(Taiwan),等公司位居世界航运公司前,20,强。,集装箱制造业,近年来集装箱产量,在目前的管理水平下，每,TEU,集装箱约使用油漆,65Kg,。,集装箱涂料现状,集装箱涂料市场份额,集装箱涂料现状,集装箱结构,集装箱生产工艺,集装箱涂料现状,集装箱涂料配套,涂料品种,干膜厚度（,m,）,内表面,外表面,1,环氧富锌车间底漆,10,10,2,环氧富锌底漆,20,20,3,环氧内面漆,45,4,环氧中间漆,4,0,5,丙烯酸面漆（氯化橡胶面漆）,40,合计,75,1,1,0,集装箱涂料的沿革,涂料,1960 1980 1990 2004,面漆,醇酸,氯化橡胶,丙烯酸,中间漆,环氧,底漆,醇酸等,氯化橡胶,环氧,环氧富锌,With the improvment of container owners requirment,the coating system tend to a uniform,which is“epoxy zinc rich primer+epoxy mid-coat+acrylic top-coat”.,氯化橡胶和丙烯酸面漆对比,品种,氯化橡胶,丙烯酸,防腐性,好,稍差,施工性,差,好,柔韧性,好,差,成本,稍高,较低,丙烯酸面漆的缺陷,柔韧性差,丙烯酸面漆的缺陷,防腐性略差,盐雾,600hr,氯化橡胶面漆 丙烯酸面漆,氯化橡胶面漆的缺陷,环保问题,柔韧性-增韧剂的选择,施工性能遇水泛白,施工性能修补时的色差,氯化橡胶面漆的缺陷,施工性能,修补时的色差,光泽差异造成造成视觉色差,咬底,当用醇酸树脂作为增塑剂时，堆场修补（下线,8,小时至,24,小时）会出现咬底，影响施工进度。,氯化橡胶面漆的缺陷,施工性能,遇水泛白,氯化橡胶面漆的改进方向,采用环保的方法生产氯化橡胶树脂,降低成本,选用合适的增塑剂,集装箱涂料标准,-,Konstandt Lab,Test,Test method,Evolution&Requirement,Result,Score,Abrasion resistance,ASTM D 1044,1000cycles,250g,CS 10 wheel,0-10,11-25,25,10,8,6,Corrosion resistance,Rust from scribe mark,ASTM B117,ASTM 1654,0,1.0mm,2.0mm,3.0mm,4.0mm,5.0mm,6.0mm,10,8,7,6,5,4,4,Blister,ASTM B117,ASTM 1654,None,1-2,3-7,8-10,11-25,26-40,10,7,7,6,4,3,Test,Test method,Evolution&Requirement,Result,Score,Accelerated weathering,Color change,ASTM E 42,(600hr),ASTM D 2244,E2,E3,10,6,Loss in gloss,ASTM E 42,(600hr),ASTM D 523,0-10%,11-24%,25%,10,8,6,Flexibility,ASTM D 1713,180 deg.12.5mm,Original,No cracking,Slight cracking,Cracking,10,5,1,After accelerated weathering(600hr,),No cracking,Slight cracking,Cracking,10,5,1,集装箱涂料标准,-,Konstandt Lab,Test,Test method,Evolution&Requirement,Result,Score,Adhesion,DIN 53151,划格附着力,Original,No removal,5%removal,15%removal,35%removal,50%removal,10,8,6,4,2,After accelerated weathering,(600hr),No removal,5%removal,15%removal,35%removal,50%removal,10,8,6,4,2,Salt water resistance,5%NaCl,168hr,25,No effect,Slight dulling,Blistering and/or other defects,10,6,2,集装箱涂料标准,-,Konstandt Lab,Test,Test method,Evolution&Requirement,Result,Score,Impact resistance,ASTM 2794,Cm-Kg at Failure,Original,75,63-74,50-62,50,10,8,6,4,After accelerated weathering(600hr),75,63-74,50-62,50,10,8,6,4,Hardness,ASTM D 3363,(Pencil scratch),Oxidized and,catalyzed coatings,6H,5H,4H,3H,10,6,4,2,Evaporation coatings,4H,3H,2H,H,10,8,6,4,集装箱涂料标准,-,Konstandt Lab,IICL,：,INSTITUTE OF INTERNATIONAL CONTAINER LESSORS,集装箱涂料标准,-,IICL,IICL,全称为国际集装箱出租商协会,成立于,1971,年，本部设立于华盛顿，随着第一代集装箱和集装箱船的快速发展，集装箱的安全和质量成为集装箱货运体系中至关重要的一个环节。在美国，,IICL,同美国国务院和海岸巡逻队一同制定国际集装箱安全公约（,CSC,）的各项条款和美国集装箱安全法案,Panel Specimen,Size:76*152*1.6mm,Sbustrate:G3101(SS41),Blasted:Sa2,Rough,：,25-40 Rmax 80,集装箱涂料标准,-,IICL,Exterior Method,8h UV at 60,（,UVA340,）,4h condensation at 50,Repeat sub cycle for 72hrs,4h wet at 30,2h dry at 40,Repeat sub cycle for 96hrs,8 Times,56days,集装箱涂料标准,-,IICL,4h wet at 30,2h dry at 40,Repeat sub cycle for 96hrs,8 Times,56days,Interior Method,8h dry/dark at 60,4h condensation(,100%RH,)at 60,Repeat sub cycle for 72hrs,集装箱涂料标准,-,IICL,Blister Test(ASTM D714),No.10,No.8,No.6,No.4,No.2,None,20,Few,15,10,5,0,Medium,10,5,0,Medium Dense,5,0,Dense,0,集装箱涂料标准,-,IICL,Rust Test(ASTM D610),COSCO KANSAI,Rust Grade,Unit Value,Grade 10,10,Grade 9,9,Grade 8,6,Grade 7,3,Grade 6,0,集装箱涂料标准,-,IICL,Undercutting Test (ASTM D1654),Average Scribe Creep,Unit Value,0-1mm,10,2-3mm,9,4-6mm,7,7-9mm,5,10-11mm,3,11mm,0,集装箱涂料标准,-,IICL,Adhesion Test,（,ASTM D3359,）,ASTM Classification,Unit Value,5B,15,4B,12,3B,7,2B,3,1B or 0B,2,集装箱涂料标准,-,IICL,Impact Resistance Test(ASTM D 2794),Exterior/Interior Reverse Impact,Kg M at Failure,Unit Value,0.23,10,0.17-0.22,8,0.12-0.16,6,0.06-0.11,4,0.03-0.05,2,0.02 or Less,0,集装箱涂料标准,-,IICL,Impact Resistance Test(ASTM D 2794),Interior Forward Impact,COSCO KANSAI,Kg M at Failure,Unit Value,0.58,10,0.52-0.57,9,0.46-0.51,8,0.40-0.45,7,0.35-0.39,6,0.29-0.34,5,0.28 or Less,0,集装箱涂料标准,-,IICL,Abrasion Test(ASTM D4060),COSCO KANSAI,Weight Loss,Unit Value,0-100mg,15,101-150mg,12,151-200mg,9,200mg,0,集装箱涂料标准,-,IICL,Color Test,（,ASTM D2244,）,Color Change,（,E,）,Unit Value,3,3,4,2,5,1,5,0,集装箱涂料标准,-,IICL,Gloss Test(ASTM D523),涂膜
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