014RhodiaSolv_罗地亚绿色溶剂的应用_09模版课件

Cliquez et modifiez le titre,Cliquez pour modifier les styles du texte du masque,Deuxime niveau,Troisime niveau,Quatrime niveau,Cinquime niveau,Responsible for Eco Friendly Solution,罗地亚农用化学品配方,绿色溶剂在农药配方中的应用,-,Rhodiasolv,201,1,年,9,月，北京,主要内容,1.,传统溶剂的主要缺陷,2.,何谓绿色溶剂,3.,Rhodiasolv,绿色溶剂介绍,Rhodiasolv,Polarclean,Rhodiasolv,ADMA,Rhodiasolv,Green 25,Rhodiasolv,RPDE,4.,Rhodiasolv,与传统溶剂的溶解性能比较,溶剂在植保方面的关键作用,溶剂的选择直接关系到制剂的性能,液体剂型配方中首要考虑因素,溶剂在作物保护方面起到关键作用,合成,化学反应,及副产物,稀释液,有效成分的含量,化学稳定性,提高性能,润湿,粘着,渗透,传导,耐雨水冲刷,名称,CAS No.,危害等级,危害分类,警告标记,EPA,状态,二甲基甲酰胺,(,DMF,),68-12-2,T (,有毒,),易燃性液体,:,类别,3,;,生殖毒性,2,类,;,Acute,Tox. 4; Eye Irrit.,2;,H226,H319, H312, H332, H360D,T,生殖毒性,2,类,.,R61-R20/21-R36,危险,无,N-,甲基,-2-,吡咯烷酮,(NMP),872-50-4,T (,有毒,),Eye Irrit. 2; Skin Irrit. 2;,H319, H315,T,生殖毒性, 2,类,.,R61 -,R36/37/38,警告,EPA List 3,Nonfood,环己酮,108-94-1,Xn (,有害,),易燃,闪点,44C;,易燃性液体,:,类别,3,;,Acute Tox. 4;,H226, H332,Xn, R10 - R20,警告,EPA List 2,Nonfood,异佛尔酮,78-59-1,Xn (,有害,),H319, H302, H312, H335,H351,Xn,致癌,:,类别,3, R21/22 -,R36/37 - R40,警告,EPA List 1 Nonfood,甲醇,67-56-1,F (,极其易燃,),T (,有毒,),闪点,11C,易燃性液体,:,类别,2,;,STOT SE 1;,Acute Tox. 3;,H225, H301,H311, H331, H370,F,T,R11 - R23/24/25 -R39/23/24/25,危险,EPA List 3 Nonfood,传统溶剂的,主要缺陷,*,from Sigma-Aldrich msds,暂无统一明确的定义,普遍认为应该具有下述部分,/,全部特性,何为,“,绿色溶剂,”,?,无,VOC (,VOC:,挥发性有机含碳化合物,),无生态毒性,对人畜安全,天然可再生,快速生物降解,不易燃,与,HSE,法律法规相符合,最大的应用来自乳油,EC,还包括,:,水乳,EW,和微乳,ME,浓可溶剂,SL,专用助剂,既可作主溶剂，亦可作助溶剂,作助溶剂可以有效改进农药活性成分的溶解性能,传统助溶剂,:,环己酮,异佛尔酮,甲醇,NMP (N-,甲基,-2-,吡咯烷酮,), DMF,(,二甲基甲酰胺,),等,使用绿色溶剂的主要剂型,Rhodiasolv,Polar,c,lean,：化学结构,纯度,: 98 %,全球专利保护,M,e,O,N,M,e,2,O,O,E,s,t,e,r,a,m,i,d,e,M,e,O,O,M,e,O,O,I,r,i,s,+,M,e,2,N,H,M,e,2,N,N,M,e,2,O,O,D,i,a,m,i,d,e,+,Rhodiasolv,Polarclean,物 性 数 据,分子量,187.8,折射率, n,D,at 20C,1.4610 0.0005,比重,at 20C,1.048 0.001 g/cm3,表面张力,36.3 0.3 mN/m,沸点,(1013 hPa),280 2 C,蒸汽压,(20C), 0.01 Pa,动态粘度,(23C),9.82 0.02 mPa.s,凝固点, 100 mg/l,藻类生长潜力测试,OECD 201,CE50 (72h) 100 mg/l,鱼类急性毒性测试,OECD 203,LC50 (96h) 100 mg/l,固有生物降解性,OECD 302B,96%,，,28,天,急性皮肤刺激测试,OECD 404,非皮肤刺激物,离体急性眼睛刺激测试,(BCOP test),OECD 437,对眼睛无损害,活体急性眼睛刺激测试,OECD 405,对眼睛有刺激,(R36),皮肤过敏性测试（局部的淋巴节化验）,OECD 429,非皮肤致敏物,急性经口毒性（大鼠试验）,OECD 423, 2000 mg/Kg,细菌基因突变测试（,Ames,实验）,OECD 471,无诱变性,Rhodiasolv,Polar,c,lean,:,安全又环保,毒性和生态毒性数据,Rhodiasolv,Polar,c,lean,:,同大多数有机溶剂互溶,(50/50 by volume at room temperature),室温下,50:50,体积比,溶剂,溶剂,现象,现象,Rhodiasolv,Polarclean,： 参考配方,氯氰菊酯,10% ME,配方组成,%,氯氰菊酯,原药,92%,11,Antarox B/848,25,水,34,Rhodiasolv Polarclean,30,性能,:,比重, 20,C,pH,稀释稳定性,透明稳定,(,硬水,A,/,D,/,C,5%, 30,C,18,hr,),功夫菊酯,2.5% EC,配方组成,%,功夫菊酯原药, 95.4%,2.7,Geronol CH/850,1,0,Rhodiasolv Polarclean,补足,性能,:,比重, 20,C,5,pH, 4.,1,稀释稳定性,稳定,(,硬水,A,/,D,/,C,5%, 30C, 2hr,),Rhodiasolv,Polarclean,： 参考配方,乙氧氟草醚,23,%,EC,配方组成,%,乙氧氟草醚原药,(,9,5,%,)2,Geronol,TBE-724,10,Rhodiasolv,Polarclean,Rhodiasolv ADMA1040,性能,:,比重, 20,C, 1.,1,pH,稀释稳定性,稳定,(,硬水,A,/,D,/,C,5%, 30,C,2,hr,),2,4-D,异辛酯,60,% EC,配方组成,%,2,4-D,异辛酯,原药,(90%),67,Geronol CH/150,1,2.5,Alkamuls OR/36,7.5,Rhodiasolv Polarclean,补足,性能,:,比重, 20,C, 1.,12,pH,稀释稳定性,稳定,(,硬水,A,/,D,/,C,5%, 30C, 2hr,),强极性，水溶性，绿色溶剂,农药配方中的强力助溶剂（,EC/EW/ME/SL,等）,Hansen,溶解度参数接近于传统极性溶剂,(,NMP, DMF,DMAC,),杰出的毒性和生态毒性表现,不易燃，蒸汽压非常低（低,VOC,）,Rhodiasolv,Polarclean:,主要优点,Rhodiasolv,ADMA,：主要特性,ADMA(,烷基二甲基酰胺,),N, N-,二甲基辛酰胺,CAS no. 1118-92-9,N, N-,二甲基癸酰胺,CAS no.,14433-76-2,主要特性,适合各类农药活性成分,抑制晶体增长,中等极性,不易溶于,水,高沸点，不易燃,低倾点,Rhodiasolv,ADMA,：,基本物性数据,Rhodiasolv,ADMA 10,Rhodiasolv,ADMA 810,化学成分,N.N-,二甲基癸酰胺,N.N-,二甲基癸酰胺,N.N-,二甲基辛酰胺,外观,25,C,无色到浅黄色透明液体,水分,(Karl Fisher), %,0.3,色泽,(APHA),100,粘度,20,C,(mPa.s), 110,倾点,(,C,), -10 (ADMA 10) -15 (ADMA 810),生物降解性,易生物降解,溶解性,水中溶解度, 0.2% (ADMA 10) 0.5% (ADMA 810),溶于主要极性和芳烃溶剂,EPA,许可,40 CFR 180.920,可用于收割前的庄稼,戊唑醇,250 g/L EC,配方,戊唑醇,原药,95%,g/L,Rhodiasolv ADMA 10,Rhodiasolv Polarclean,255,Geronol TEB-25,100,性质,:,比重 20,C,pH (5%),乳化性能,(,0.5% & 5%,30,C,),2hr: (A, D, C):,0, 0, 0.,无晶体析出,24hr: (A, D, C):,0, 0, 0.,无晶体析出,Rhodiasolv,ADMA,不溶于,水,的中等极性溶剂,EC,配方中,ADMA,与,Polarclean,的组合协同效应,Rhodiasolv,ADMA,：,参考配方,甜菜宁,9% +,甜菜宁,7%,+,乙呋草磺,11% EC,配方,%,乙呋草磺,原药,97% 11.5,甜菜宁,甜菜宁,Rhodiasolv Polarclean 5,油酸甲酯,柠檬酸,水,不溶,水,溶,Polarclean,ADMA,可调的溶解性能,戊唑醇,250 g/L E,W,配方,戊唑醇,原药,95%,g/L,Rhodiasolv ADMA 10,3,50,Rhodiasolv Polarclean,1,5,0,Geronol,EW/36,200,水,30,性质,:,比重 20,C,0.99,pH (5%),乳化性能,(,0.5% & 5%,30,C,),2hr: (A, D, C):,0, 0, 0.,无晶体析出,24hr: (A, D, C):,0, 0, 0.,无晶体析出,Rhodiasolv,ADMA,：,参考配方,三,唑醇,23,% EC,配方,%,三,唑醇,原药,AntaroxB/848 10,Rhodiasolv ADMA 810 17,性质,:,比重 20,C,pH (5%),乳化性能,(,5%,30,C,),2hr: (A, D, C):,0,.5, 0,.1, 0.,无晶体,Rhodiasolv,Green 25,物 性 数 据,外观,20C,无色到浅黄色透明液体,水分,(%),200,-20,1.09,100,微溶,无,Rhodiasolv DIB,273,N/V,0.95,100,几乎不溶,无,Rhodiasolv RPDE,为低成本无毒的绿色溶剂，具有中等溶解力，可以作为主溶剂应用在不需要极高极性的农药配方中。,Rhodiasolv DIB,性质与,Rhodiasolv RPDE,相似，极性和水溶性均略低于,RPDE,，挥发性更低。配方中加入少量,DIB,可以明显地抑制晶体的增长。,Rhodiasolv,RPDE,：农药上的应用,部分农药的溶解度数据（,25,度）,甲草胺,743 g/l,甜菜宁,65 g/l,氯苯嘧啶醇,126 g/l,敌稗,543 g/l,配方举例,氟硅唑,420g/L,EC,氟硅唑,(93.2%)451 g/l,Rhodacal 60/BE 50,Soprophor BSU50,Rhodiasolv RPDE,补足,氟硅唑,10%EW,氟硅唑,(93.2%)110 g/l,Rhodiasolv RPDE,275,Soprophor 60/BE20,Soprophor 4D38450,Ag-Rho Pol 23W(2%) 120,丙二醇,50,水补足,溶解度试验结果,0 =,常温不溶解,1 =,7,天稳定,(,常温,),2 =,7,天稳定,(0),3 =,7,天稳定,(0,加晶种,),.,Rhodiasolv,与传统溶剂的溶解性对比,R,hodiasolv,Polarclean,0,3,2,1,0,3,2,1,异佛尔酮,Al,achlor 48%,Tebuconaz,ole,25%,Difenoconazole,25%,P,henmedipham,16%,Propanil,36%,Triflur,alin 40%,Oxyfluorf,en,22%,Propo,xur 20%,Chlorpyrifos,40%,Alpha-Cypermethrin,10%,P,endimethalin,33%,Tr,iadimenol,23%,0,3,2,1,Al,achlor 48%,Tebuconaz,ole,25%,Difenoconazole,25%,P,henmedipham,16%,Propanil,36%,Triflur,alin 40%,Oxyfluorf,en,22%,Propo,xur 20%,Chlorpyrifos,40%,Alpha-Cypermethrin,10%,P,endimethalin,33%,Tr,iadimenol,23%,Al,achlor 48%,Tebuconaz,ole,25%,Difenoconazole,25%,P,henmedipham,16%,Propanil,36%,Triflur,alin 40%,Oxyfluorf,en,22%,Propo,xur 20%,Chlorpyrifos,40%,Alpha-Cypermethrin,10%,P,endimethalin,33%,Tr,iadimenol,23%,NMP,0,3,2,1,Al,achlor 48%,Tebuconaz,ole,25%,Difenoconazole,25%,P,henmedipham,16%,Propanil,36%,Triflur,alin 40%,Oxyfluorf,en,22%,Propo,xur 20%,Chlorpyrifos,40%,Alpha-Cypermethrin,10%,P,endimethalin,33%,Tr,iadimenol,23%,R,hodiasolv,ADMA,Hansen,溶解度参数,真溶剂,非溶剂,极性项,d,P,R,色散项,d,D,d,H,d,D,d,P,氢键,项,d,H,每个溶剂组分的总内聚能可以从三个方面来表征,分别是,色散项,(D),极性项,(,P,),以及氢键,项,(H).,聚合体也通过内聚能来表征,以溶解度大小及一个半径来表示,.,H,P,D,d,d,d,H,P,D,d,d,d, R,10,20,30,0,10,20,30,氢键能,(J/cm,3,),1/2,极性参数,(J/cm,3,),1/2,Hexylene glycol,Glycerol carbonate,Diethylene glycol,RPDE,Glycerol,DMSO,NMP,Ethyl diglycol,Cyclohexyl acetate,IRIS,Triacetin,Acetonitrile,Methanol,Toluene,Perchlorethylene,THF,EA,Ethyl levulinate,MPA,MEK,Acetone,Cyclohexanone,E. lactate,DMF,Ether-alcohols,Dichloromethane,Anisole,Heptane,DIB,Ethylene carbonate,Propylene carbonate,PolarClean,AUGEO 191,Isophorone,Green 25,水溶性,极性,ADMA,Green 25,Polarclean,ADMA,NMP,环己酮,2- ethyl,hexanol,Rhodiasolv,与,传统溶剂,:,Hansen,溶解度参数坐标,异佛尔酮,有害溶剂,一般溶剂,绿色溶剂,Rhodiasolv,已经全面本地化生产,罗地亚镇江,Rhodiasolv,Green 25,Rhodiasolv,Green 2,1,Rhodiasolv,RPDE,罗地亚飞翔,生产基地,Rhodiasolv,Polarclean,Rhodiasolv,ADMA 810,Rhodiasolv,ADMA 10,本地生产，更经济,交货周期短,供货安全有保障,可持续发展,罗地亚公司文化的核心理念,谢谢！,