014rhodiasolv_罗地亚绿色溶剂的应用_09[精彩]

Cliquez et modifiez le titre,Cliquez pour modifier les styles du texte du masque,Deuxime niveau,Troisime niveau,Quatrime niveau,Cinquime niveau,Responsible for Eco Friendly Solution,罗地亚农用化学品配方,绿色溶剂在农药配方中的应用,-Rhodiasolv,2011年9月，北京,殖唁烷扯丝烤简焦围硅锄断枢洱靶筹栖祭季蒂讫晋大猎剁呆介拧绷拨泉赴014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,主要内容,1.,传统溶剂的主要缺陷,2.,何谓绿色溶剂,3. Rhodiasolv,绿色溶剂介绍,Rhodiasolv,Polarclean,Rhodiasolv,ADMA,Rhodiasolv,Green 25,Rhodiasolv,RPDE,4.,Rhodiasolv,与传统溶剂的溶解性能比较,拯娜乾加激番痊债吕北比逐混荔伯谁夷拈埂低睫诫常供怎掘讲淄稗搓淌帽014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,溶剂在植保方面的关键作用,溶剂的选择直接关系到制剂的性能,液体剂型配方中首要考虑因素,溶剂在作物保护方面起到关键作用,合成,化学反应,及副产物,稀释液,有效成分的含量,化学稳定性,提高性能,润湿, 粘着, 渗透,传导, 耐雨水冲刷,乖梧毗帐暂帆却娟观压来藐晨箭憨资伪套撮鞍修肘侨款趾旋胡微饼嵌他奉014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,名称,CAS No.,危害等级,危害分类,警告标记,EPA状态,二甲基甲酰胺,(DMF),68-12-2,T (有毒),易燃性液体: 类别3,; 生殖毒性, 2类;,Acute Tox. 4; Eye Irrit. 2;,H226, H319, H312, H332, H360D,T,生殖毒性, 2类.,R61-R20/21-R36,危险,无,N-,甲基,-2-,吡咯烷酮,(NMP),872-50-4,T (有毒),Eye Irrit. 2; Skin Irrit. 2;,H319, H315,T,生殖毒性, 2类.,R61 - R36/37/38,警告,EPA List 3,Nonfood,环己酮,108-94-1,Xn (有害),易燃, 闪点44C;,易燃性液体: 类别3;,Acute Tox. 4;,H226, H332,Xn, R10 - R20,警告,EPA List 2,Nonfood,异佛尔酮,78-59-1,Xn (有害),H319, H302, H312, H335, H351,Xn,致癌: 类别3, R21/22 -,R36/37 - R40,警告,EPA List 1 Nonfood,甲醇,67-56-1,F (极其易燃),T (有毒),闪点 11C, 易燃性液体: 类别2;,STOT SE 1; Acute Tox. 3;,H225, H301,H311, H331, H370,F,T,R11 - R23/24/25 -R39/23/24/25,危险,EPA List 3 Nonfood,传统溶剂的,主要缺陷,* from Sigma-Aldrich msds,射缴秒侍冗羚轨粪酝剥孩讽楞女逢埋卯豺滁奖嚷举蘑畏霄嫉詹欺挠瓣貉伙014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,暂无统一明确的定义,普遍认为应该具有下述部分/全部特性,何为 “绿色溶剂”?,无VOC (VOC: 挥发性有机含碳化合物),无生态毒性,对人畜安全,天然可再生,快速生物降解,不易燃,与HSE法律法规相符合,避搂秒效赣香淀根屠盎设汰竭应靛刷洞蝶衷猖牛韵炕臂低苦料胶岳田早胀014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,最大的应用来自乳油EC,还包括,:,水乳,EW,和微乳,ME,浓可溶剂,SL,专用助剂,既可作主溶剂，亦可作助溶剂,作助溶剂可以有效改进农药活性成分的溶解性能,传统助溶剂,:,环己酮,异佛尔酮,甲醇,NMP (N-,甲基,-2-,吡咯烷酮,), DMF,(,二甲基甲酰胺,),等,使用绿色溶剂的主要剂型,坟邯屠曲碉况守记占竞酶约巧皆终冤秤厉瓦檬悸倡限著官腰丁菌她木驻子014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Rhodiasolv,Polar,c,lean,：化学结构,纯度: 98 %,全球专利保护,M,e,O,N,M,e,2,O,O,E,s,t,e,r,a,m,i,d,e,M,e,O,O,M,e,O,O,I,r,i,s,+,M,e,2,N,H,M,e,2,N,N,M,e,2,O,O,D,i,a,m,i,d,e,+,疚撕挖橙勤柳礼锁漠制屏琼威令柞钉馅娟谁娄拌只逃韭卿捡颤耿芋佩泛鳞014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Rhodiasolv,Polarclean,物 性 数 据,分子量,187.8,折射率, n,D,at 20C,1.4610 0.0005,比重,at 20C,1.048 0.001 g/cm3,表面张力,36.3 0.3 mN/m,沸点,(1013 hPa),280 2 C,蒸汽压,(20C), 0.01 Pa,动态粘度,(23C),9.82 0.02 mPa.s,凝固点, 100 mg/l,藻类生长潜力测试,OECD 201,CE50 (72h) 100 mg/l,鱼类急性毒性测试,OECD 203,LC50 (96h) 100 mg/l,固有生物降解性,OECD 302B,96%,，,28,天,急性皮肤刺激测试,OECD 404,非皮肤刺激物,离体急性眼睛刺激测试,(BCOP test),OECD 437,对眼睛无损害,活体急性眼睛刺激测试,OECD 405,对眼睛有刺激(R36),皮肤过敏性测试（局部的淋巴节化验）,OECD 429,非皮肤致敏物,急性经口毒性（大鼠试验）,OECD 423, 2000 mg/Kg,细菌基因突变测试（Ames 实验）,OECD 471,无诱变性,Rhodiasolv Polarclean: 安全又环保,毒性和生态毒性数据,锣屋升驰送拉吾谤拭河紧奇什旦寓踏伦夏卯剐牡痈镐贯烃查勺褐础兹摇踢014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Rhodiasolv Polarclean: 同大多数有机溶剂互溶,(50/50 by volume at room temperature),室温下50:50体积比,溶剂,溶剂,现象,现象,递贱蹦捷粤邀演咨桨君禹嫌丧韦魂癸掺箭菱仅荣搅驹啊慨掺沈嚼诣键冉浆014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Rhodiasolv,Polarclean,： 参考配方,氯氰菊酯 10% ME,配方组成 %,氯氰菊酯原药, 92%11,Antarox B/84825,水 34,Rhodiasolv Polarclean30,性能:,稀释稳定性 透明稳定,(硬水A/D/C, 5%, 30C, 18hr),功夫菊酯 2.5% EC,配方组成%,功夫菊酯原药, 95.4% 2.7,Geronol CH/850 10,Rhodiasolv Polarclean 补足,性能:,稀释稳定性 稳定,(硬水 A/D/C, 5%, 30C, 2hr),纪枯痉绥驳姑恨感位宗盔愁俩鳃徐皖茅漆枷厦褪壤漂芭斩谓华该空富涉蘸014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Rhodiasolv,Polarclean,： 参考配方,乙氧氟草醚 23% EC,配方组成 %,Geronol TBE-72410,Rhodiasolv ADMA1040,性能:,稀释稳定性 稳定,(硬水A/D/C, 5%, 30C, 2hr),2,4-D 异辛酯 60% EC,配方组成%,2,4-D 异辛酯原药(90%) 67,Geronol CH/150 12.5,Alkamuls OR/36 7.5,Rhodiasolv Polarclean 补足,性能:,稀释稳定性 稳定,(硬水 A/D/C, 5%, 30C, 2hr),从汝雁域驶厩恍桨释艾欢意蜜逊斧陶房稀抨骤弟温辆莆免滨址斌琐欢愚试014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,强极性，水溶性，绿色溶剂,农药配方中的强力助溶剂（EC/EW/ME/SL等）,Hansen溶解度参数接近于传统极性溶剂,(,NMP, DMF,DMAC,),杰出的毒性和生态毒性表现,不易燃，蒸汽压非常低（低VOC）,Rhodiasolv,Polarclean:,主要优点,谊坯矢妆孩钨业艇晒赃舰凄域臂逊酬瓷邵酮蒸么郎湾楞寝忿泄叼格膘嘎荆014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Rhodiasolv,ADMA,：主要特性,ADMA(,烷基二甲基酰胺,),N, N-,二甲基辛酰胺,CAS no. 1118-92-9,N, N-,二甲基癸酰胺,CAS no. 14433-76-2,主要特性,适合各类农药活性成分,抑制晶体增长,中等极性,不易溶于,水,高沸点，不易燃,低倾点,茎憾劝运冈雅嘲魏凭职项朽傀沃恿昔繁粒巍妈尊赎劫鲤玉盖镁恳关眼懒球014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Rhodiasolv,ADMA,：基本物性数据,Rhodiasolv,ADMA 10,Rhodiasolv,ADMA 810,化学成分,N.N-二甲基癸酰胺,N.N-二甲基癸酰胺,N.N-二甲基辛酰胺,外观 25,C,无色到浅黄色透明液体,水分 (Karl Fisher), %, 0.3,色泽 (APHA), 100,粘度 20,C,(mPa.s), 110,倾点 (,C,), -10 (ADMA 10) -15 (ADMA 810),生物降解性,易生物降解,溶解性,水中溶解度 0.2% (ADMA 10) 0.5% (ADMA 810),溶于主要极性和芳烃溶剂,EPA许可,40 CFR 180.920, 可用于收割前的庄稼,消个玩恼殉肤叮诫泅耍盗框霄习佛杰缄茁垦疮竭萍迪镜氦毕收褪评搭至傀014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,戊唑醇 250 g/L EC,配方,戊唑醇原药 95% 263.2 g/L,Rhodiasolv Polarclean255,Geronol TEB-25 100,性质:,比重 20C 1.002,乳化性能 (0.5% & 5%, 30C),2hr: (A, D, C): 0, 0, 0. 无晶体析出,24hr: (A, D, C): 0, 0, 0. 无晶体析出,Rhodiasolv ADMA,不溶于水的中等极性溶剂,EC配方中ADMA与 Polarclean的组合协同效应,Rhodiasolv,ADMA,：参考配方,甜菜宁 9% +甜菜宁 7%,+ 乙呋草磺11% EC,配方 %,乙呋草磺原药 97% 11.5,Rhodiasolv Polarclean 5,水,不溶,水,溶,Polarclean,ADMA,可调的溶解性能,吓吮虞卵磋爆熬霹帐决狰矿嫉和鹅上牡骂抱熄庞属女旗楼那身甜阻亦君究014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,戊唑醇 250 g/L EW,配方,戊唑醇原药 95% 263.2 g/L,Rhodiasolv ADMA 10350,Rhodiasolv Polarclean150,Geronol EW/36 200,水30,性质:,比重 20C 0.99,乳化性能 (0.5% & 5%, 30C),2hr: (A, D, C): 0, 0, 0. 无晶体析出,24hr: (A, D, C): 0, 0, 0. 无晶体析出,Rhodiasolv,ADMA,：参考配方,三唑醇 23% EC,配方 %,AntaroxB/848 10,Rhodiasolv ADMA 810 17,性质:,比重 20C 1.06,乳化性能 (5%, 30C),2hr: (A, D, C): 0.5, 0.1, 0. 无晶体,绣组孔赎静触带湘脓舍愈迟庚泡债蓖彤郧栗都养此如拭基苟舜鸟赡扰病叶014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Rhodiasolv,Green 25,物 性 数 据,外观,20C,无色到浅黄色透明液体,水分,(%),200,-20,1.09,100,微溶,无,Rhodiasolv DIB,273,N/V,0.95,100,几乎不溶,无,Rhodiasolv RPDE 为低成本无毒的绿色溶剂，具有中等溶解力，可以作为主溶剂应用在不需要极高极性的农药配方中。,Rhodiasolv DIB性质与Rhodiasolv RPDE相似，极性和水溶性均略低于RPDE，挥发性更低。配方中加入少量DIB可以明显地抑制晶体的增长。,历阻谗雪锥戮蝎滥拷坯宿树垂妊坟铃健皖腾章休配蹬淘倚掏慑戌户穗祭悠014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Rhodiasolv,RPDE ：农药上的应用,部分农药的溶解度数据（25度）,甲草胺,743 g/l,甜菜宁65 g/l,氯苯嘧啶醇 126 g/l,敌稗,543 g/l,配方举例,氟硅唑 420g/L EC,氟硅唑 (93.2%)451 g/l,Rhodacal 60/BE 50,Soprophor BSU50,Rhodiasolv RPDE补足,氟硅唑 10%EW,氟硅唑 (93.2%)110 g/l,Rhodiasolv RPDE275,Soprophor 60/BE20,Soprophor 4D38450,Ag-Rho Pol 23W(2%) 120,丙二醇50,水补足,储欲健拜兴考蒙珐辫莎塘反泣瘁柯唤撼沽师逝登渤盲焉嵌振食黎厌缆涌禾014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,溶解度试验结果,0 = 常温不溶解,1 = 7天稳定(常温),2 = 7天稳定(0),3 = 7天稳定(0加晶种),.,Rhodiasolv 与传统溶剂的溶解性对比,R,hodiasolv,Polarclean,0,3,2,1,0,3,2,1,异佛尔酮,Al,achlor 48%,Tebuconaz,ole,25%,Difenoconazole,25%,P,henmedipham,16%,Propanil,36%,Triflur,alin 40%,Oxyfluorf,en,22%,Propo,xur 20%,Chlorpyrifos,40%,Alpha-Cypermethrin,10%,P,endimethalin,33%,Tr,iadimenol,23%,0,3,2,1,Al,achlor 48%,Tebuconaz,ole,25%,Difenoconazole,25%,P,henmedipham,16%,Propanil,36%,Triflur,alin 40%,Oxyfluorf,en,22%,Propo,xur 20%,Chlorpyrifos,40%,Alpha-Cypermethrin,10%,P,endimethalin,33%,Tr,iadimenol,23%,Al,achlor 48%,Tebuconaz,ole,25%,Difenoconazole,25%,P,henmedipham,16%,Propanil,36%,Triflur,alin 40%,Oxyfluorf,en,22%,Propo,xur 20%,Chlorpyrifos,40%,Alpha-Cypermethrin,10%,P,endimethalin,33%,Tr,iadimenol,23%,NMP,0,3,2,1,Al,achlor 48%,Tebuconaz,ole,25%,Difenoconazole,25%,P,henmedipham,16%,Propanil,36%,Triflur,alin 40%,Oxyfluorf,en,22%,Propo,xur 20%,Chlorpyrifos,40%,Alpha-Cypermethrin,10%,P,endimethalin,33%,Tr,iadimenol,23%,R,hodiasolv,ADMA,虑奠悯耗缩侩靠吵骚构山阻柯与儒溢伎薪空裔馒栋巧戎峡倡辈桩亮拉八嘻014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Hansen,溶解度参数,真溶剂,非溶剂,极性项, dP,R,色散项, dD,d,H,d,D,d,P,氢键项, dH,每个溶剂组分的总内聚能可以从三个方面来表征, 分别是色散项(D), 极性项(,P,)以及氢键项(H).,聚合体也通过内聚能来表征, 以溶解度大小及一个半径来表示.,H,P,D,d,d,d,H,P,D,d,d,d, R,婪慑缓着楔源缨靳逗沈厢江渺遏会牙戍煽晨充烷迟惯描晋臭屑玩酉瓜畅惮014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,10,20,30,0,10,20,30,氢键能,(J/cm3)1/2,极性参数,(J/cm3)1/2,Hexylene glycol,Glycerol carbonate,Diethylene glycol,RPDE,Glycerol,DMSO,NMP,Ethyl diglycol,Cyclohexyl acetate,IRIS,Triacetin,Acetonitrile,Methanol,Toluene,Perchlorethylene,THF,EA,Ethyl levulinate,MPA,MEK,Acetone,Cyclohexanone,E. lactate,DMF,Ether-alcohols,Dichloromethane,Anisole,Heptane,DIB,Ethylene carbonate,Propylene carbonate,PolarClean,AUGEO 191,Isophorone,Green 25,水溶性,极性,ADMA,Green 25,Polarclean,ADMA,NMP,环己酮,2- ethyl hexanol,Rhodiasolv与传统溶剂: Hansen溶解度参数坐标,异佛尔酮,有害溶剂,一般溶剂,绿色溶剂,铁怯另崇谩击惩涸棋炽崩傣蚀绍屈扦宦贰瓢寓项娄其蹦揍孵睡幽燕佣端堆014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,Rhodiasolv 已经全面本地化生产,罗地亚镇江,Rhodiasolv Green 25,Rhodiasolv Green 21,Rhodiasolv RPDE,罗地亚飞翔,生产基地,Rhodiasolv Polarclean,Rhodiasolv ADMA 810,Rhodiasolv ADMA 10,本地生产，更经济,交货周期短,供货安全有保障,颜婆丙捆杏送溪徒浦援像珠苍笑考服恢磷渣芳升谁夜侍阮耗练服庆较盗市014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,可持续发展,罗地亚公司文化的核心理念,谢谢！,结返石孔扣捻额与恿林绊匹舅撰舍祷疾喜彩兴玲阻团谚杂褥冤靡串页豆浙014RhodiaSolv_罗地亚绿色溶剂的应用_201109014RhodiaSolv_罗地亚绿色溶剂的应用_201109,