资源描述
有机氟化学 (II)有机所氟化学实验室标志性成果黄维垣 先生： 亚磺化脱卤反应陈庆云 先生： 三氟甲基化反应 ACS Award for Creative Work in Fluorine Chemistry1972 George H. Cady1973 Joseph H. Simons1974 William T. Miller1975 Joseph D. Park1976 Paul Tarrant1977 Charles B. Colburn1978 Jeanne M. Shreeve1979 Wayne E. White1980 John L. Margrave1981 Ronald J. Gillespie1982 William J. Middleton1983 Darryl D. DesMarteau1984 Donald J. Burton1985 David C. England1986 Karl O. Christe1987 Carl G. Krespan1988 Harry J. Emleus1989 Yoshiro Kobayashi1990 J. Colin Tatlow1991 Richard D. Chambers 1992 Neil Bartlett1993 Ronald E. Banks1994 Oskar Glemser1995 Paul R. Resnick1996 Konrad Seppelt1997 Richard J. Lagow1998 Gary J. Schrobilgen1999 Herbert W. Roesky2000 William R. Dolbier, Jr.2001 Leland C. Clark, Jr.2002 David M. Lemal2003 David A. Dixon2004 Surya G.K. Prakash2005 Shlomo Rozen2006 Borisemva1. C-F 键形成反应a) 亲核氟化试剂及反应在我国氟化学工业上广泛采用aHF，KF, spray-dried KF, NaF, CsF, TBAF, TBAT, Olah Reagent, TASF, SF4,DAST, DeoxoFluor, SbF3, etc.aHF, -35 oC80 %b) 亲电氟化试剂及反应O-F ReagentsMp 147.8 oC; bp 46.7 oCCH3COOF (bp 53 oC)CF3COOFCF3OFHypofluorites 次氟酸衍生物N-F Reagents氟化能力增加
展开阅读全文