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单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,Transition Metal-Catalyzed C-H Bond Activation of Aromatic Compounds,：,Chelation-Assisted Ortho-Functionalization,Transition Metal-Catalyzed C-H,Outline,Introduction,Catalytic Ortho-Functionalization,Conclusion and Outlook,OutlineIntroduction,Introduction,Introduction,Introduction,Lewis,L.N.;Smith,J.F,J.Am.Chem.Soc.,1986,108,2728,IntroductionLewis,L.N.;Smith,Introduction,Murai,S.;et al.,Nature,1993,366,529,IntroductionMurai,S.;et al.,Introduction,Introduction,Advantages,High selectivity,Atom economy,Clean and economical process,AdvantagesHigh selectivity,Catalytic Ortho-Functionalization,Ortho-Alkylation,Ortho-Arylation,Ortho-Carbonylation,Others,Catalytic Ortho-Functionalizat,Ortho-Alkylation,Jun,C.H.,Angew.Chem.Int.Ed.,2000,39,3440,Ortho-AlkylationJun,C.H.Ang,Ortho-Alkylation,Ahrendt,K.A.;et al.,Org.Lett,.,2003,5,1301,Ortho-AlkylationAhrendt,K.A.,Ortho-Alkylation,Thalji,R.K.;et al.,J.Am.Chem.Soc.,2004,126,7192,Ortho-AlkylationThalji,R.K.;,Ortho-Alkylation,Chen X.;et al.,J.Am.Chem.Soc.,2006,128,12634,Ortho-AlkylationChen X.;et al,Ortho-Arylation,Ortho-Arylation,Ortho-Arylation,Kakiuchi,F.;et al.,J.Am.Chem.Soc.,2003,125,1698.,J.Am.Chem.Soc.,2005,127,5936,Ortho-ArylationKakiuchi,F.;e,Ortho-Arylation,Kakiuchi,F.;et al.,J.Am.Chem.Soc.,2005,127,5936,Ortho-ArylationKakiuchi,F.;e,过渡金属催化芳香化合物碳氢键活化课件,Ortho-Arylation,Wan X.B.,et al.,J.Am.Chem.Soc,.,2006,128,7416.Punna S,et al.,Synlett,2004,13,2351.Rodriguez N.;et al.,J.Org.Chem.,2004,69,8070.Shi Z J.;et al.,Angew.Chem.Int.Ed.,2007,46,5554,Ortho-ArylationWan X.B.,et a,Ortho-Arylation,Ortho-Arylation,Ortho-Arylation,Kalyani,D.;et al.,J.Am.Chem.Soc.,2005,127,7330,Ortho-ArylationKalyani,D.;et,Ortho-Arylation,Ortho-Arylation,Ortho-Arylation,Ortho-Arylation,Ortho-Arylation,Ortho-Arylation,Ortho-Arylation,Shabashov,D.;Daugulis,O.,Org.Lett.,2005,7,3657,Ortho-ArylationShabashov,D.;,Ortho-Carbonylation,Moore,E.J.;et al.,J.Am.Chem.Soc,.,1992,114,5888,Ortho-CarbonylationMoore,E.J,Ortho-Carbonylation,Fukuyama,T.;et al.,J.Org.,Chem,.,1997,62,5647,Ortho-CarbonylationFukuyama,T,Ortho-Silylation,Kakiuchi,F.;et al.,Chem.Lett,.,2001,422.,Chem.Lett,.,2002,396,Ortho-SilylationKakiuchi,F.;,Kakiuchi,F.;et al.,Chem.Lett,.,1995,681,Jia,C.;et al.,Science,2000,287,1992,Kakiuchi,F.;et al.Chem.Let,Kuninobu Y.;et al.,Angew.Chem.Int.Ed.,2007,46,6518,Kuninobu Y.;et al.Angew.Chem,Conclusion and Outlook,Outstanding results have been obtained in selectivity and atom economy.These development will help both synthetic and material chemist a great deal,Development of milder,lower temperature reaction conditions,Fine-tuning of catalyst systems to allow for the industrial use,Conclusion and OutlookOutstand,
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