个人情况综述

【个人情况综述】刘术侠，博士，教授，博士生导师。普通化学实验课程负责人。主要从事多酸合成化学、 多酸药物化学和多酸材料化学基础研究。主持或完成国家自然科学基金、教育部骨干教师基 金、科技部1035新药重大课题、吉林省科技厅重大项目等10余项，目前正在主持承担教育 部新世纪优秀人才支持计划和两项国家自然科学基金项目。至今以第一作者或通讯联系人在 国内外学术刊物上发表论文80余篇，其中被SCI收录70余篇。普通化学实验课程主持人。长期工作在本科生教学第一线，先后多轮主讲本科生无机化 学、中级无机化学、元素无机化学及无机化学实验等课程。在读博士生4人，硕士生12人。已毕业获得博士学位1人，获得硕士学位26人。【学习工作简历】1987年东北师大化学系获学士学位；1990年东北师大化学系无机化学专业获硕士学位1997年东北师大化学系无机化学专业获博士学位2001年-2002年日本东京大学访问研究1998年-2004年 东北师范大学副教授2004年-东北师范大学教授2006年-东北师范大学化学学院博士生导师。【教学工作】普通化学实验课程主持。长期工作在本科生教学第一线，先后多轮主讲本科生无机化学、中级无机化学、 元素无机化学及无机化学实验等课程。在读博士生4人，硕士生12人。已毕业获得博士学位1人，获得硕士学位26人。【主要科研方向】1. 多酸合成化学2. 多酸药物化学3. 多酸材料化学【主要科研项目】1 .教育部新世纪优秀人才支持计划项目（NCET-07-0169）,2008-2010。2. 国家自然科学基金资助项目“基于微孔金属-有机框架的多金属氧酸盐及其催化性能 研究”，2010.1-2012.12，主持。3. 国家自然科学基金资助项目“HDACi多酸前导化合物的设计合成和抗肿瘤活性”， 2009.1-2011.12，主持。4. 国家自然科学基金资助项目“以多酸为质子驱动力的有机电子给体一受体体系分子 内电子转移和结构转变” ,2006.1-2008.12,主持。（已完成）。5. 吉林省科技厅项目“固载多金属氧酸盐晶态催化剂研制及在甲醇脱水制二甲醚反应 中应用”，2009.8-2011.12,主持。6. 吉林省科技厅项目“多酸类组蛋白去乙酰酶抑制剂的合成和抗肿瘤活性”，2006.10-2008.12，主持。（已完成）。7. 吉林省科技厅重大课题“抗菌、抗病毒双重活性多酸药物的研制”，2004.10-2006.12, 主持。（已完成）。8. 国家自然科学基金资助项目”氨基酸-杂多蓝化合物的合成和抗艾滋病毒活性及机理 研究”，2001.01-2003.12,主持(已完成)。9. 国家教育部留学归国基金资助项目”以杂多酸为质子源对有机共轭体系质子驱动分 子内电子转移和结构转变”，2003.10-2004.9，主持。(已完成)。10. 吉林省科委重大课题新型稀土杂多蓝抗流感病毒药物的研究和开发， 2000.1-2002.12,主持(已完成)。【主要科研成果】近5年发表主要论文(*为通讯联系人。所列论文均为SCI检索论文)：2009 年：1. Chun-Yan Sun, Shu-Xia Liu*, Da-Dong Liang, Kui-Zhan Shao, Yuan-Hang Ren, and Zhong-Min Su* . Highly Stable Crystalline Catalysts Based on a Microporous Metal-Organic Framework and Polyoxometalates. J. Am. Chem. Soc. 2009, 131, 1883-18882. Chun-Dan Zhang, Shu-Xia Liu*, Chun-Yan Sun, Feng-Ji Ma, and Zhong-Min Su* . Assembly of Organic-Inorganic Hybrid Materials Based on Dawson-Type Polyoxometalate and Multinuclear Copper-Phen Complexes with Unique Magnetic Properties. Cryst. Growth Des. 2009, 9, 3655-36603. Hong-mei Ji, Liande Zhu, Da-dong Liang, Ying Liu, Li-li Cai, Shi-wei Zhang, Shu-xia Liu* . Use of a 12-molybdovanadate(V) modified ionic liquid carbon paste electrode as a bifunctional electrochemical sensor . Electrochim. Acta . 2009, 54, 7429-74344. Chao-ying Gao, Shu-xia Liu*, Lin-hua Xie, Chun-yan Sun, Jian-fang Cao, Yuan-hang Ren, Dan Feng and Zhong-min Su . Rational design microporous pillared-layer frameworks: syntheses, structures and gas sorption properties. CrystEngComm. 2009, 11, 177-1825. Rui-ge Cao, Shu-xia Liu*, Ying Liu, Qun Tang, Liang Wang, Lin-Hua Xie, Zhong-Min Su . Organic-inorganic hybrids constructed by Anderson-type polyoxoanionsand copper coordination complexes. J. Solid State Chem. 2009, 182, 49 - 546. Li-li Cai, Yu-xin Li*, Chao-jie Yu, Hong-mei Ji, Ying Liu, Shu-xia Liu* . Spontaneous resolution of a chiral polyoxometalate: Synthesis, crystal structures and properties. Inorg. Chim. Acta. 2009, 362, 2895-28997. Wei Zhang, Shu-xia Liu*, Dan Feng, Chun-dan Zhang, Ping Sun, Feng-ji Ma . Two novel Krebs-type polyoxoanions CuI2(WO2)2(b-XW9O33)212(X = SbIII, BiIII) resulting in 2D layer structures linked by copper(I) ions and copper(II) complex groups. J. Mol. Struct. 2009, 936, 194-1988. Ying Liu, Shu-xia Liu*, Hong-mei Ji, Shi-wei Zhang, Li-li Cai, Rui-ge Cao . Two Novel Organic-Inorganic Hybrid Compounds Constructed from Anderson-type Clusters and Transition-Metal Complexes. J. Clust. Sci. 2009, 20, 535-5439.Shi-wei Zhang, Yu-xin Li*, Ying Liu, Rui-ge Cao, Chun-yan Sun, Hong-mei Ji,Shu-xia Liu* . Synthesis and characterization of B-type Anderson polyoxoanions supported copper complexes with mixed ligands. J. Mol. Struct. 2009, 920, 284-28810. Xin-yu Zhao, Shu-xia Liu*, Yuan-hang Ren, Chao-ying Gao, Rui-ge Cao, Chaojie Yu . A 3D architecture constructed by saturated Dawson polyoxoanions and transition-metal coordination complexes CuI7(Bpy)6(BpyEt)2. J. Mol. Struct. 2009, 919, 160-16311. Ying Liu, Yu-Xin Li*, Shi-Wei Zhang, Hong-Mei Ji, Rui-Ge Cao, Shu-Xia Liu* . Organic - inorganic hybrid based on the molybdenum tellurite. J. Mol. Struct. 2009, 921, 114 -1172008 年：12. Xin-yu Zhao, Da-dong Liang, Shu-xia Liu*, Chun-yan Sun, Rui-ge Cao, Chao-ying Gao, Yuan-hang Ren, and Zhong-min Su . Two Dawson-Templated Three-Dimensional Metal-Organic Frameworks Based on Oxalate-Bridged Binuclear Cobalt(II)/Nickel(II) SBUs and Bpy Linkers. Inorg. Chem. 2008, 47(16), 7133-713813. Jian-fang Cao, Shu-xia Liu*, Rui-ge Cao, Lin-hua Xie, Yuan-hang Ren, Chao-ying Gao and Lin Xu . Organic-inorganic hybrids assembled by bis(undecatungstophosphate) lanthanates and dinuclear copper(II)-oxalate complexes. Dalton Trans. 2008, 115-12014. Yuan-Hang Ren, Shu-Xia Liu*, Rui-Ge Cao, Xin-Yu Zhao, Jian-Fang Cao, Chao-Ying Gao . Two trimeric tri-TiIV-substituted Keggin tungstogermanates based on tetrahedral linkers. Inorg. Chem. Commun. 2008, 11, 1320-132215. Ying Liu, Shu-Xia Liu*, Rui-Ge Cao, Hong-Mei Ji, Shi-Wei Zhang, Yuan-Hang Ren . Hydrothermal assembly and luminescence property of lanthanide-containing Anderson polyoxometalates. J. Solid State Chem. 2008, 181, 2237 - 224216. Xin-Yu Zhao, Shu-Xia Liu*, Yuan-Hang Ren, Jian-Fang Cao, Rui-Ge Cao, Kui-Zhan Shao . Lanthanide complexes of the monovacant Dawson polyoxotungstate a2-As2W17O6110- with 1D chain: Synthesis, structures, and photoluminescence properties. J. Solid State Chem. 2008, 181, 2488- 249317. Rui-ge Cao, Shu-xia Liu*, Lin-hua Xie, Yi-bing Pan, Jian-fang Cao, Ying Liu . Influence of different site symmetries of Eu3+ centers on the luminescence properties of Anderson-based compounds. Inorg. Chim. Acta. 2008, 361, 2013-201818. Rui-ge Cao, Shu-xia Liu*, Jian-fang Cao, Liang Wang, Qun Tang, Ying Liu, Yuan-hang Ren . An organic -inorganic hybrid compound constructed by Strandberg-type poly oxoanions and transition metal coordination complexes. J. Mol. Struct. 2008,888, 307-31219. Hai-yan Cheng, Yuan-hang Ren, Shu-xia Liu*, and Lin-hua Xie . Syntheses, Structures and Spectroscopic Characterization of Extended Waugh-Type polyoxometalates with Metal Ions as Linkers. Z. Anorg. Allg. Chem. 2008, 634, 977-98020. Chun-ling Wang, Shu-xia. Liu*, Chun-yan Sun, and Lin-hua Xie . Hydrothermal synthesis, crystal structure and fluorescence of a 3D organic-inorganic hybrid coordination network CuI(4,40-bipy)4d-Mo8O26 exhibiting an interesting polymorphism. J. Coord. Chem. 2008, 61, 891-8992007 年：21. Lin-hua Xie, Shu-xia Liu*, Chao-ying Gao, Rui-ge Cao, Jian-fang Cao, Chun-yan Sun, and Zhong-min Su . Mixed-Valence Iron(II, III) Trimesates with Open Frameworks Modulated by Solvents. Inorg. Chem. 2007, 46, 7782-778822. Rui-ge Cao, Shu-xia Liu*, Lin-hua Xie, Yi-bing Pan, Jian-fang Cao, Yuan-hang Ren, and Lin Xu . Organic-Inorganic Hybrids Constructed of Anderson-Type Polyoxoanions and Oxalato-Bridged Dinuclear Copper Complexes. Inorg. Chem. 2007, 46, 3541-354723. Chao-ying Gao, Shu-xia Liu*, Lin-hua Xie, Yuan-hang Ren, Jian-fang Cao and Chun-yan Sun . Design and construction of a microporous metal-organic framework based on the pillared-layer motif. CrystEngComm. 2007, 9, 545-54724. Da-Dong Liang, Shu-Xia Liu*, Chun-Ling Wang, Yuan-Hang Ren . A novelnanomolecularorganic-inorganichybridcompound: Na2NH(CH2CH2OH)34Mo36O112(OH2)14OHCH2CH2NH(CH2CH2OH)22.nH2O (n 72) exhibiting a supramolecular one-dimensional chainlike structure. J. Solid State Chem. 2007, 180(2), 558-56325. Da-Dong Liang, Shu-Xia Liu*, Yuan-Hang Ren, Chun-Dan Zhang, Lin Xu .Mo18O54(VO4)26-: A conventional Dawson structure with unpredicted transition metal hetero-atoms based on VO4 tetrahedra. Inorg. Chem. Commun. 2007, 10(8), 933-93526. Hai-Yan Cheng, Shu-Xia Liu*, Lin-Hua Xie, YQan-Hang Ren, and Chun-Dan Zhang .Synthesis, Crystal Structure, and Properties of a Supramolecular Compound Based on Waugh-type Polyanion and Moroxydine, Chem. Lett. 2007, 36 (6), 746-74727. Chun-Dan Zhang, Shu-Xia Liu*, Bo Gao, Chun-Yan Sun, Lin-Hua Xie, Miao Yu, Jun Peng . Hybrid material based on metal-organic coordination complex and cage-like polyoxovanadate clusters: Synthesis, characterization and magnetic properties. Polyhedron 2007, 26 ，1514-152228. Chun-Ling Wang, Shu-Xia Liu*, Lin-Hua Xie, Yuan-Hang Ren, Da-Dong Liang, Chun-Yan Sun, Hai-Yan Cheng . New 3D two-fold interpenetrating polyoxometallate compounds built up of dititanium-substituted Keggin polyoxotungstates and transition metals. Polyhedron 2007, 26(13), 3017-302229. Miao Yu, Lin-hua Xie, Shu-xia Liu*, Chun-ling Wang, Hai-yan Cheng, Yuan-hang Ren, Zhong-min Su . Photoluminescent metal-organic framework with hex topology constructed from infinite rod-shaped secondary building units and single e,e-trans-1,4-cyclohexanedicarboxylic dianion. Inorg. Chim. Acta. 2007, 360 (9), 3108-311230. Chun-Ling Wang, Shu-Xia Liu*, Chun-Yan Sun, Lin-Hua Xie, Yuan-Hang Ren, Da-Dong Liang, Hai-Yan Cheng . Bimetals substituted germanotungstate complexes with open Wells-Dawson structure: Synthesis, structure, and electrochemical behavior of M(H2O)(g-H2O)2KM(H2O)4(Ge2W18O66)11- (M = Co, Ni, Mn). J. Mol. Struct. 2007, 841(1-3), 88-9531. Lin-hua Xie, Shu-xia Liu*, Rui-ge Cao, Chao-ying Gao, and Jian-fang Cao . A Double Chain Metal-organic Framework Constructed by Tetrameric Nickel(II) Units and 1,3,5-Benzenetricarboxylic Trianions. Z. Anorg. Allg. Chem. 2007, 633, 2049205232. Chun-Yan Sun, Shu-Xia Liu*, Chun-Ling Wang, Lin-Hua Xie, Chun-Dan Zhang, Bo Gao and En-Bo Wang . Reactions of trivacant lone-pair-containing tungstobismutate and electrochemical behaviors of its sandwich-type products. J. Coord. Chem. 2007, 60(5), 567-57933. Bo Gao, Shu-Xia Liu*, Chun-Dan Zhang, Lin-Hua Xie, Chun-Yan Sun and Miao Yu . Hydrothermal assembly of pyrite-related framework: (NH4)2Ni(H2O)32-TeW6O24.H2O. J. Coord. Chem. 2007, 60(8), 911-9182006 年：34. Shu-xia Liu*, De-hui Li, Lin-hua Xie, Hai-yan Cheng, Xin-yu Zhao, and Zhongmin Su , Two-Dimensional Lanthanide Heteropolyvanadates of Manganese(IV) and Nickel(IV) Containing Two Types of Heteropoly Anions with 1:13 and 1:12 Stoichiometry. Inorg. Chem. 2006, 45, 8036-804035. Chun-yan Sun, Shu-xia Liu*, Lin-hua Xie, Chun-ling Wang, Bo Gao, Chun-dan Zhang,Zhong-min Su . Synthesis and characterization of one- to three-dimensional compounds composed of paradodecatungstate-B cluster and transition metals as linkers. J. Solid State Chem.2006, 179, 2093-210036. Bo Gao, Shu-xia Liu*, Lin-hua Xie, Miao Yu, Chun-dan Zhang, Chun-yan Sun, Hai-yan Cheng . Hydrothermal assembly of (3,6)-connected networks with classical mineral structures constructed from Anderson type heteropolymolybdate and metal cations. J.Solid State Chem. 2006, 179, 1681-168937. Chun-Yan Sun, Shu-Xia Liu*, Chun-Ling Wang, Lin-Hua Xie, Chun-Dan Zhang, Bo Gao,Zhong-Min Su, Heng-Qing Jia . Synthesis, structure and characterization of a new co-containing germanotungstateswithopenwellsDawsonstructure:K13Co(H2O)(m-H2O)2K(Ge2W18O66). J. Mol. Struct. 2006, 785, 170-1752005 年：38. Shu-xia Liu*, Lin-hua Xie, Bo Gao, Chun-dan Zhang, Chun-yan Sun, De-hui Lia and Zhong-min Su . (Cover Paper) An organic-inorganic hybrid material constructed from threedimensional coordination complex cationic framework and entrained hexadecavanadate clusters. Chem.Commun. 2005, 5023-502539. Lin-hua Xie, Shu-xia Liu*, Bo Gao, Chun-dan Zhang, Chun-yan Sun, De-hui Li, and Zhong-min Su . A three-dimensional porous metal-organic framework with the rutile topology constructed from triangular and distorted octahedral building blocks. Chem. Commun. 2005, 2402 -240440. Bo Gao, Shu-xia Liu*, Lin-hua Xie, Xiao-hong Wang, Chun-dan Zhang, Chun-yan Sun, Ning-hai Hu, Heng-qing Jia . A novel organically templated three-dimensional open framework vanadium tellurite: (NH3CH2CH2NH3)2V2Te6O18. J. Solid State Chem. 2005, 178, 182540. De-hui Li, Shu-xia Liu*, Chun-yan Sun, Lin-hua Xie, En-bo Wang, Ning-hai Hu,Heng-qing Jia . novel 2D layered network based on 13-vanadomanganate(IV):K3(HABOB)4MnV13O38-9H2O(ABOB=N-amidino-4-morpholincarboxamidine). Inorg. Chem. Commun. 2005, 8, 433 - 43641. Chun-Dan Zhang, Shu-xia Liu*, Lin-Hua Xie, Bo Gao, Chun-Yan Sun, De-Hui Li . A new two-fold interpenetrated three-dimensional compound based on metal-organic coordination polymers and (V4O12) clusters: Cu(bipy)4V4O122H2O (bipy=4,4 -bipyridine). J. Mol. Struct. 2005, 753, 40-44.发明专利：1、抗耐青霉素肺炎链球菌(PRSP)的多酸化合物及其制备方法。发明人：刘术侠，白 云鹏，翟宏菊，杜宏明，李德慧，梁大栋。专利号：ZL200410011104.92、一种纯净杂多蓝的制备方法。发明人：刘术侠。专利号：ZL200410011150.93、组蛋白去乙酰化酶抑制剂有机锡多酸化合物及其制备方法。发明人：刘术侠，黄百 渠，张春丹，陆军，王春玲，陈玉丽。申请号：200710056078.54、高分散固载Keggin型多金属氧酸盐晶态催化剂的制备方法。发明人：刘术侠 梁大 栋，孙春艳，苏忠民。申请号：200810051479.6【鉴定成果目录】1.吉林省科技厅重大课题“抗菌、抗病毒双重活性多酸药物的研制（合同号： 20040402-5）”，吉科鉴字2006第254号，2006年12月，国际先进。第1完成人。2.吉林省科技厅基础课题“多酸类组蛋白去乙酰酶抑制剂的合成和抗肿瘤活性（合同号: 20060562）”，吉科鉴字2009第093号，2008年12月，国际先进。第1完成人。【获奖情况】1.吉林省科学技术进步一等奖,2007年，获奖人:苏忠民，许林，王恩波,刘术侠，彭军，王新龙, 康振辉，颜力楷