仿香技术在特色烟用香料开发中的应用研究ppt课件

单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,仿香技术在特色烟用香料开发中的应用研究,曾晓鹰 尹开云 肖维毅 陈岭峰,昆明卷烟厂 技术中心,云南瑞升科技有限公司,Dec.,2004,GUANGZHOU,分析科学的发展使香料的研究开发，特别是仿香技术进入全新的发展空间。,Major Advances in Instrumentation,In Recent 50 Years,分析技术的进步使我们发现更多的东西,1956 First Demonstration of GC/MS,（,Bendix,Corporation,）,1956,年以前，调香师用鼻子仿香,GC/MS,分析技术的出现使仿香成为一门科学,基于,GC/MS,分析的仿香技术,简单成分的仿香可全权委托,GC/MS,复杂成分的仿香必须依靠,GC/MS,GC/MS,可以精确定量,烟用香料的发展趋势,天然化,提取自天然植物（果类）,提取自烟草,特色化,独特香气,独特效果,安全性,谐调性,不可模仿性,特色烟用香料的开发思路,取之于烟草，不完全依赖烟草,取自天然,有选择补加显效成分,独特的香气风格,难于复制和模仿,应用,GC/MS,分析和仿香技术开发特色烟用香料的技术原理,1,、通过,GC/MS,分析获得优质烟草的挥发性化学成分图谱。,2,、通过自行研制开发的设备提取昆烟烟末制备烟用香料，分析精油获得其挥发性化学成分图谱。,3,、比对,1,和,2,的精油图谱，找出差异作为人工补香的技术依据。,4,、以昆烟烟末制备的香料为底物，补加人工合成的烟草关键香气成分，得到目标香料。,5,、比对目标香料和优质烟草挥发性化学成分的图谱并反复修正。,优质津巴布韦烟叶,依托于,GC/MS,分析,的仿香技术,KM2,KM1,分析,分析,比对,比对,分析,仿香香精,制造工艺流程图,(Manufacturing Processing),预处理除杂 加入溶剂,A,超滤脱色素和粗纤维,烟叶原料,均质原料,提取液,A1,提取液,A2,真空浓缩,脱除蜡质,/,油脂 脱除蛋白质,/,多糖,/,多酚,烟草香料产品,提取液,B2,提取液,B1,浓缩物,A,真空浓缩 低温超滤 加入溶剂,B,特色烟用香料提取设备：提取,/,分离,/,浓缩,Extraction/Separation/Concentration,仿香设计工作室,烟用香料香味特征,名称,外观状态,香味特征,LB,1,红棕色浸膏状流体,陈酿津巴布韦烟草甜润、醇和的自然香韵。,KM,1,浅红棕色浸膏状流体,烟草香，略甜，无陈酿津巴布韦烟草特征香味。,KM,2,红棕色浸膏状流体,烟草香，甜润，具有津巴布韦烟草醇和的自然香韵。,香料,LB1,挥发性成分总离子流图,仿香目标,:,香料,LB1,香料,KM1,挥发性成分总离子流图,仿香基础,:,香料,KM1,仿香配方设计（）,序号,化合物名称,用量（,g,）,1,2-,乙酰基吡啶,0.3,2,2-,乙酰基吡咯,0.35,3,面包酮,0.8,4,糠醛,4.5,5,丁内酯,1.7,6,ALPHA-,蒎烯,0.25,7,苯甲醛,1,8,环戊烯醇酮,1.3,9,2-,乙酰基呋喃,0.7,10,2,，,6-,庚二烯醛,0.7,11,2-,羟基,-3-,甲基,-2-,环戊烯,-1-,酮,0.3,12,苯甲醇,8,13,苯乙醛,2.5,14,香叶醛,0.6,15,苯乙醇,6,16,2,，,6,，,6-,三甲基,1,，,4-,环己二酮,1,17,胡椒薄荷酮,1,18,柠檬醛,1.4,19,壬酸,1.7,20,吲哚,0.5,仿香配方设计（）,序号,化合物名称,用量（,g,）,21,7,，,8-,环氧,-ALPHA-,紫罗兰酮,1.5,22,茄尼酮,30,23,BETA-,大马酮,13,24,香叶基丙酮,14,25,DHA,8,26,巨豆三烯酮,40,27,3-,氧代,-ALPHA-,紫罗兰酮,3,28,C14,酸,3,29,金合欢基丙酮,28,30,十六酸甲酯,2,31,C16,酸,1,32,3-,呋喃甲醇,0.3,33,乙酸异戊酯,0.2,34,己酸,1.5,35,辛酸,1.3,36,藏红花醛,0.7,37,-,辛内酯,0.2,38,-,壬内酯,0.1,39,壬酸乙酯,1.7,40,诺卡酮,3,41,丁酸乙酯,0.3,序号,化合物名称,用量（,g,）,42,3-,甲基丁酸,0.2,43,3-,甲基戊酸,0.15,44,5-,甲基糠醛,2.5,45,仿樟醇,0.12,46,丁香酚,0.1,47,-,紫罗兰酮,0.1,48,苄酸苄酯,0.45,49,PG,补足,1000,仿香配方设计（,3,）,香料,KM2,挥发性成分总离子流图,仿香产品,:,香料,KM2,LB1,、,KM1,、,KM2,三种烟用香料的挥发性香味成分,PK,RT,中文名,化学式,Area%,LB,1,KM,1,KM,2,1,3.2,异戊烯醛,C,5,H,8,O,0.02,0.01,0.03,2,3.38,丁酸乙酯,C,6,H,12,O,2,0.04,0.02,0.05,3,3.47,2-,甲基四氢呋喃,-3-,酮,C,5,H,8,O,2,0.09,0.02,0.07,4,3.84,糠醛,C,5,H,4,O,2,0.86,0.27,0.95,5,3.91,3-,甲基丁酸,C,5,H,10,O,2,0.11,0.03,0.15,6,4.14,3,-,呋喃甲醇,C,5,H,6,O,2,0.2,-,0.03,7,4.38,环己基甲基醛,C,8,H,14,0,-,0.03,0.03,8,4.49,乙酸异戊酯,C,7,H,14,O,2,0.01,-,0.02,9,4.61,2-,环戊烯,1,4-,二酮,C,5,H,4,O,2,0.58,0.15,0.65,10,5.09,2-,乙酰基呋喃酮,C,6,H,6,O,2,0.07,0.03,0.05,11,5.12,丁内酯,C,4,H,6,O,2,0.09,0.04,0.13,12,5.63,3-,甲基戊酸,C,6,H,12,O,2,0.07,0.04,0.12,13,5.75,2,-,吡啶甲醛,C,6,H,5,NO,0.02,-,0.01,14,5.97,苯甲醛,C,7,H,6,O,0.05,0.05,0.07,15,6.01,5-,甲基糠醛,C,6,H,6,O,2,0.1,0.04,0.23,16,6.34,己酸,C,6,H,12,O,2,0.27,-,0.15,17,6.42,6-,甲基,-5-,庚烯,-2-,酮,C,8,H,14,O,0.08,0.07,0.07,18,6.53,6-,甲基,-5-,庚烯,-2-,醇,C,8,H,16,O,0.04,0.02,0.05,19,6.62,庚二烯醛,C,7,H,10,O,0.01,-,0.01,20,6.67,烟碱醛,C,6,H,5,NO,0.04,0.02,0.03,PK,RT,中文名,化学式,Area%,LB,1,KM,1,KM,2,21,6.86,吡咯醛,C,5,H,5,NO,0.09,0.05,0.04,22,7.19,2-,乙基己醇,C,8,H,18,O,-,0.03,0.02,23,7.32,苯甲醇,C,7,H,8,O,0.97,0.41,1.23,24,7.51,苯乙醛,C,8,H,8,O,0.42,0.5,0.65,25,7.84,2-,乙酰基吡咯,C,6,H,7,NO,0.69,0.29,0.85,26,7.91,1,2,-,环戊二酮,C,5,H,6,O,2,0.07,-,0.02,27,7.98,3-,甲基苯甲醛,C,8,H,8,O,0.03,-,0.01,28,8.12,5-,羟基,-2,（,5H,）,-,呋喃酮,C,4,H,4,O,3,-,0.09,0.07,29,8.41,3,4-,二氢,-6-,甲基,-2H-,吡喃,C,6,H,10,O,-,0.02,0.03,30,8.42,2-,甲基环庚酮,C,8,H,14,O,0.06,-,0.04,31,8.53,芳樟醇,C,10,H,18,O,0.11,0.07,0.13,32,8.61,壬醛,C,9,H,18,O,0.04,0.06,0.07,33,8.65,6-,甲基,-,3,5,-,庚二烯,-,2,-,酮,C,8,H,12,O,0.04,-,0.02,34,8.81,苯乙醇,C,8,H,10,O,-,0.33,0.43,35,9.01,N-,甲基吡咯醛,C,6,H,7,NO,0.12,0.07,0.9,36,9.37,4,-,氧化异胡尔酮,C,9,H,12,O,2,-,0.08,0.05,37,9.38,萘酮,C,9,H,12,O,2,0.19,-,0.03,38,9.64,2-,壬烯醛,C,9,H,16,O,0.09,-,0.07,39,9.87,辛酸,C,8,H,16,O,2,0.13,-,0.06,40,9.96,异苯并二氢吡喃,C,9,H,10,O,0.06,-,0.03,LB1,、,KM1,、,KM2,三种烟用香料挥发性香味成分,PK,RT,中文名,化学式,Area%,LB,1,KM,1,KM,2,41,10.1,2,-,异丙基,-,5,-,氧,-,己醛,C,9,H,16,O,2,0.06,-,0.06,42,10.25,松油醇,C,10,H,18,O,0.04,-,0.05,43,10.43,藏红花醛,C,10,H,14,O,0.1,-,0.08,44,10.74,2-,烯丙级环己酮,C,9,H,14,O,6,0.06,-,0.01,45,10.8,胡薄荷酮,C,10,H,16,O,0.08,-,0.06,46,11.43,-,辛内酯,C,8,H,14,O,2,0.07,-,0.05,47,11.56,壬酸,C,9,H,18,O,2,0.14,-,0.11,48,11.92,-,壬内酯,C,9,H,16,O,2,0.1,-,0.13,49,12.51,法呢醇,C,15,H,26,0,0.04,-,0.03,50,13.13,丁香酚,C,10,H,12,O,2,0.08,0.06,0.14,51,13.2,癸酸,C,10,H,20,O,2,3.14,0.09,2.13,52,13.26,茄酮,C,13,H,22,O,-,2.85,2.01,53,13.56,对,-,孟,-,1-,(,7),-,烯,-,9,-,醇,C,10,H,18,O,-,0.16,0.09,54,13.61,-,大马酮,C,13,H,18,O,3.28,1.47,2.45,55,14.08,二氢大马酮,C,13,H,20,O,-,0.32,0.26,56,14.09,-,紫罗兰酮,C,13,H20O,0.72,-,0.62,57,14.49,香豆素,C,9,H,6,O,2,-,0.22,0.32,58,14.63,香叶基丙酮,C,13,H,22,O,1.0,0.49,0.89,59,15.15,巴豆酸薄荷酯,C,14,H,24,0,2,-,0.18,0.12,60,15.23,-,紫罗兰酮,C,13,H,20,O,1.66,1.23,LB1,、,KM1,、,KM2,三种烟用香料挥发性香味成分,PK,RT,中文名,化学式,Area%,LB,1,KM,1,KM,2,61,16.14,二氢猕猴桃内酯,C,11,H,16,O,2,0.98,0.57,0.98,62,16.7,巨豆三烯酮,A,C,13,H,18,O,1.02,0.52,1.03,63,17.08,巨豆三烯酮,B,C,13,H,18,O,4.05,1.98,3.26,64,17.37,-,红没药醇,C,15,H,26,O,-,0.04,0.02,65,17.77,巨豆三烯酮,C,C,13,H,18,O,0.73,0.41,0.56,66,18.02,巨豆三烯酮,D,C,13,H,18,O,2.63,1.35,3.12,67,19.69,十四酸甲酯,C,15,H,30,O,2,-,0.12,0.07,68,20.32,十四酸