【JIS日本标准】JIS Z 84623： Capability of detectionPart 3：Methodology for determination of

Z 8462-32005 (ISO 11843-32003) 12 1 (JSA) ISO 11843-3:2003Capability of detection Part 3: Methodology for determination of the critical value for the response variable when no calibration data are used JIS Z 8462-3 A BJIS Z 8462 JIS Z 8462-1 1 JIS Z 8462-2 2 JIS Z 8462-3 3 1Z 8462-32005 (ISO 11843-32003) 11. 22. 23. 34. 34.1 34.2 34.3 35. yc 45.1 45.2 55.3 6 A 7 B8JISZ 8462-32005(ISO 11843-32003) 3 Capability of detectionPart 3 : Methodology for determination of the critical value for the response variable when no calibration data are used 2003 1 ISO 11843-3:2003Capability of detectionPart 3: Methodology for determination of the critical value for the response variable when no calibration data are used JIS Q 0030 JIS Z 8461 2Z 8462-32005 (ISO 11843-32003)1. 5.1 JIS Z 8462-2 ISO/IEC Guide 21 IDTMODNEQISO 11843-3:2003Capability of detectionPart 3: Methodology for determination of the critical value for the response variable when no calibration data are used (IDT)2. JIS Q 0030 ISO Guide 30Terms and definitions used in connection with reference materials JIS Z 8101-1 1 ISO 3534-1StatisticsVocabulary and symbolsPart 1 : Probability and general statistical termsJIS Z 8101-2 2 ISO 3534-2StatisticsVocabulary and symbolsPart 2: Statistical quality control JIS Z 8101-3 3 ISO/FDIS 3534-3StatisticsVocabulary and symbolsPart 3: Design of experiments JIS Z 8402-2:1999 2 ISO 5725-2:1994Accuracy (trueness and precision) of measurement methods and resultsPart 2:Basic method for the determination of repeatability and reproducibility of a standard measurement method JIS Z 8461:20013Z 8462-32005 (ISO 11843-32003) ISO 11095:1996Linear calibration using reference materials JIS Z 8462-1:2001 1 ISO 11843-1:1997Capability of detectionPart 1: Terms and definitions JIS Z 8462-2:2003 2 ISO 11843-2:2000Capability of detectionPart 2: Methodology in the linear calibration case ISO 5479:1997Statistical interpretation of dataTests for departure from the normal distribution3. JIS Z 8101JIS Q 0030JIS Z 8402-2JIS Z 8461JIS Z 8462-1 ISO 5479 4.4.1 4.2 JIS Z 8462-2 4.1 4.34.3.1J J 30 95 30 4Z 8462-32005 (ISO 11843-32003) s5.2 sb 1 s s s vs221 (v ) yc | x = 0) (1)P( ya yc | x = 0) x = 0 ya yc 5Z 8462-32005 (ISO 11843-32003) 3 a)y 0 b)c)(1)(2)yc = yb z1 01 + 1J K (2)z1- 1 0Jyb K 0 v s0 z1- t y = y t(v)s1 + 1 (3)cb10 JK (2)0b b sb 0 5.2 ISO 5479 J y b =J y jj =1J y y y0 sb =J ( y j yb ) 2j =1J 1 y b 6Z 8462-32005 (ISO 11843-32003)y = y t(v)s1 + 1 (4)cb1b JK v = J 1 JIS Z 8462-1 0.05 t (2)(5) 1 yc = yb t1(v)sb1 + 1 (5)J (2)5.3 J sb K 0.05 1 1 JK (0.05) ybyasbyc K 7Z 8462-32005 (ISO 11843-32003) Ab2J j = 12J KPssst t W=xyybyaycyj yoz 1 1 = J 1t 2 0b 28Z 8462-32005 (ISO 11843-32003) BB.1 1 ICP-AES BCR BCR: Community Bureau of Reference European Commission (Belgium) CRM 142 BCR CRM 142 light sandy soil0.5 g 10 1 25 mL 24 ICP-AES 226 nm J30 B.1 CRM 142 226 nm mV2.1702.2112.2062.2292.2152.2102.1912.1892.2152.1862.1832.1892.1452.1592.2092.1692.1942.1882.2032.1922.1912.2032.1752.2032.1742.1932.1712.1822.1782.172= 29 = 0.05 t t1-() = t0.95(29) =1.699 yb =2.189 8 mV sb = 0.018 6 mV 3 2.177 mV2.183 mV2.161 mV(4) 3 3 11yc =2.189 8+1.6990.018 6 =2.189 8+0.019 1 mV=2.209 mV B.2 +mV3039Z 8462-32005 (ISO 11843-32003) B.2 CRM 142 226 nm yc3030.052.189 8 mV2.173 7 mV0.0186 mV2.209 mV (0.815 mV) 0.027 mV IACR B.2 2 (III) COD JIS JIS K 0102 3 17.19.20.20 (CODCr) (III) (II)30 0.060 mol/L (III) B.3 B.3 mL19.7719.7119.7719.9419.9219.8419.7719.7119.7719.9119.9519.8819.7819.7119.8519.9419.9419.7719.7819.8019.8519.9119.9419.7619.7619.8319.7819.9119.8319.80= = 0.01 b2 = 1.737 1.79 5.12= = 0.05 W = 0.904 5 =10Z 8462-32005 (ISO 11843-32003)0.01 0.900= 0.05 0.927 1 yb = 19.829 mL sb = 0.077 4 mL 29= 0.05 t ()t1 - (v) = t0.95 (29) = 1.699(5) 2yc =19.8291.6990.077 4=19.8290.133 7 mL=19.70 mL B.4 1 + 1 mL30 B.4 yc3010.0519.829 mL0.077 4 mL19.70 mL0.060 mol/L III 19.70 mL ISO/TC 147