杜邦产品介绍

Click to edit Master title style,Click to edit Master text styles,Second level,Third level,Fourth level,Fifth level,杜邦工程塑料,产品介绍,Copyright 2001 E. I. du Pont de Nemours and Company. All rights reserved. DuPont Engineering Polymers.,DuPont Engineering Polymers,Product Portfolio,HTN,高温尼龙,Zytel,DMX,尼龙,Minlon,矿物增强尼龙,Delrin,聚甲醛,Hytrel,热塑性聚酯弹性体,Vespel,polyimide,型材,Zenite,LCP,液晶聚合物,Rynite,PET,热塑性饱和聚酯,Crastin,PBT,热塑性饱和聚酯,Registered trade name of DuPont,Zytel,尼龙树脂,热塑性塑料的类别划分,Zenite,LCP,无定型聚合物,结晶聚合物,通用塑料,工程塑料,特种聚合物,Teflon,& Tefzel,Fluoropolymers,Hytrel,Thermoplastic Polyester,Elastomer,Vespel,PI,Zytel,HTN,Zytel,& Minlon,Polyamide,Delrin,Polyacetal,Crastin,& Rynite,Polyester,POM,PA,PET,PBT,PC,PPO,PS,ABS,PMMA,SAN,PVC,PP-GF,PE-UHMW,PP,PE-HD,PE-LD,PSU,PES,PPSU,LCP,PTFE,PI,HPPA,TPE,Registered trade name of DuPont,Engineering Polymers,W,e will be the,全球第一的半结晶型工程塑料供应商,CLEAR # 1 GLOBAL SUPPLIER OF SEMI-CRYSTALLINE ENGINEERING POLYMER PRODUCTS,by delivering superior value to customers,STRATEGIC INTENT,IN 1931 DUPONT,卡 乐 斯 博 士,DR CAROTHERS,INVENTED NYLON FIBER.,1931,年杜邦卡乐斯博士发明了尼龙,IN 1934 NOBEL WINNER DR.PAUL FLORY JOINNED DUPONT IN CARATHERS GROUP.,1934,年诺贝尔奖金得主弗洛瑞教授加入杜邦并在卡乐斯博士的小组工作,IN 1938 DUPONT STARTED NYLON PRODUCTION.,1938,年杜邦开始生产尼龙,ENGINEERING POLYMER HISTORY,IN 1937 GERMANY IG FARBEN,斯 齐 拉 克,INVENTED NYLON6 BY CAPROLACTAM RING OPENING POLYMERIZATION AND STARTED NYLON6 PRODUCTION IN 1942,。,1937,年德国斯齐拉克发明尼龙,6,并于,1942,年工业化。,IN 1959 DUPONT STARTED POM PRODUCTION,。,1959,年杜邦发明聚甲醛工业化。,IN 1962 CELANESE STARTED POM COPOLYMER PRODUCTION1962,年,.,塞拉尼斯开始生产共聚甲醛,ENGINEERING POLYMER HISTORY,IN 1958 BAYER STARTED POLYCARBONATE PRODUCTION. 1958,年拜尔公司开始生产聚碳酸,IN 1966 GE STARTED MPPO PRODUCTION. 1966,年,GE,开始生产,MPPO,聚苯醚,IN 1970 CELANESE STARTED PBT PRODUCTION 1970,年塞拉尼斯开始生产,PBT,IN ABOUT 1975 DUPONT STARTED PET ENGINEERING POLYMER PRODUCTION.,1975,年杜邦开始生产,PET,工程塑料,ENGINEERING POLYMER HISTORY,尼龙由杜邦公司的,Wallace Hume Carothers,于 193,1,-1935发明,并于1938年投入商业化应用.,Zytel,/ Minlon,尼龙树脂,什么是尼龙?,尼龙又名聚酰胺,是分子结构中含有下列重复酰胺基团的聚合物 ,Nylon = Polyamide = PA,酰胺基团,HO,NC,尼龙的化学结构,缩聚反应合成 脂肪族尼龙,二元胺 + 二元酸,聚合 水解,聚酰胺(尼龙) + 水,在二元胺与二元酸中含有的碳原子的数目决定了尼龙的名称,Nylon (PA) -,不同种类的尼龙,PA 66/6,PA 6,PA 66,PA 612,特殊类别,PA 12,PA 11,HPPA,Nylon ,具有以下突出的性能,强度, 韧性,耐化学性,耐热性,易于成型,具有突出的尺寸稳定性,和耐化学性,具有卓越的,韧性,具有优越的耐热性,吸水性小,具有突出的刚性和强度,刚性与韧性的,完美结合,具有,极好的尺寸稳,定性,可快速成型,流动性好,Minlon,Zytel ST,Zytel HTN,High,Productivity,Zytel PA 612,GRZ,Zytel,DMX,Unique Characteristics,杜邦公司的,Zytel,尼龙的性能特点,强度, 韧性,耐化学性,耐热性,易于成型,“,行业领头羊,”,尼龙改性手段,热稳定,成核促进,光稳定,抗水解,增韧,阻燃,增加润滑性,增加刚性:玻纤矿物,Minlon,Kevlar,纤维,Zytel,/ Minlon,在汽车上的应用,Radiators,水室,Air intake manifolds,进气歧管,Rocker covers,气门室盖,Wheel,covers,车轮盖,Fans /,shrouds,风扇、风圈,Silencers,消音器,Zytel,/ Minlon,在电子/电器中的应用,Transformercomponents,变压器组件,Connectors,连接器,Coil bobbins,线圈骨架,Encapsulations,塑封材料,Wall,sockets,开关面板,Zytel,/ Minlon,在其他行业的应用,Chain saw parts,电动链锯部件,Bicycle wheels,自行车轮,Fasteners,紧固件,Cable ties,扎带,Furniture,parts,家具部件,Garden hose,connectors,花园管接头,Sports,equipm,ent,运动器材,DuPont,尼龙的种类 / 规格,66666/6612,HTN51HTN52,Basic101151,Lubricated,101L,7331F,151L101F,Heat Stabilized,103HSL,153HSL,Hydro. Resist.122L,High Prod.,FE3756,Tough,408,FE18502,Super Tough,ST801,ST811,FlexibleFN714FN727FN718,Plasticized301P91AHS350P,Flame Retardant,FR15,DMX, ST,DMX ST601H,Nylon,Type,Zytel,Grade,DuPont,尼龙的种类 / 规格,66666/6612,HTN51HTN52,Glass Reinforced,70G,73G,74G,77G,51G52G,Mineral Reinf.,11C40,FE16501,10B40,Min, GR22CFE622820B,T, GR71G,ST, GR,80G,82G,DMX, GR,DMX 61G,FR, GR,FR50,FE19015,FR51GFR52G,FR, MinFR70M30V0,ST, Min,12T,Nylon,Type,Zytel,Grade,Delrin,聚甲醛树脂,Delrin,acetal,由杜邦在 50年代末期发明,.,Acetal ,均聚甲醛和共聚甲醛在结构上的区别,higher crystallinity,& mechanical properties,lower crystallinity,Hydrogen atom,Hydrogen bonding,Oxygen atom,Carbon atom,H,HHO,|,|,CH,3, O,C O ,C O .C O C CH,3,|,|,H,HH,n,均聚,Formaldehyde,molecule,共聚,Comonomer group,Formaldehyde molecules,H,HH,H,HHHH,|,|,|,|,CH,3, O,C O ,CC O,C O ,CC O .,CC OH,|,|,|,|,H,HH,H,HHHH,n,n,聚甲醛的典型性能,优点:,无须增强，天生具有极高刚性,在广泛的温度范围内具有高韧性,使用温度范围广,抗疲劳性能好,抗蠕变性好,尺寸稳定性好，吸水率低,耐化学性和耐燃油性好,摩擦系数小,有,FDA,认可,可提供抗,UV,等级,具有极好的染色性,局限性:,最大的长期使用温度 90; 最大的短时耐热温度 120 ,C,无阻燃等级,抗水解性不够好 (热水),缺口敏感性差,可抗强酸和强碱,常用于替代:,金属 (重量, 耐磨性, 耐腐蚀),聚酰胺 (尺寸稳定),均聚甲醛和共聚甲醛在性能上的区别,71,65,25,10,13,7,0,20,40,60,80,100,拉伸强度,(,MPa),屈服点伸长率,(%),冲击强度,(,kJ/m2),3100,2700,模量,(,MPa),Delrin,100,高粘度共聚甲醛,聚甲醛的改性,增加结晶程度,低磨耗,增韧改性,抗,UV,性,玻纤填充及增强,抗静电,挤出,成型周期短，收缩小,机械强度更高,增加润滑性,减少与金属&塑料接触时的磨损,增加强度和模量,可抵抗更高的温度,抗 紫外线,在受紫外线照射时保持强度,提高冲击强度,低模量，高弹性,管，棒及型材的挤出,可进行机加工,碳黑填充改性,抗静电剂的使用,Delrin,聚甲醛材料的标准等级,Highlighted grades are new commercial offerings.,“100”“300”“500”“900”“1700” /“2700”,高粘度,中-高中低粘度,超高高冲击粘度粘度高流动流动,通用级100500900 高性能等级,II 100,高成型 加工性,100,P500P900P1700P,Enhanced ELEVEN111P,511P,911P,111DP 311DP,共聚物,2700,挤出级,II 150 SAII 550II 150 E,Delrin,甲醛材料改性等级,Highlighted grades are new commercial offerings.,Flow Series,“100”“300”“500”“900”“1700”,冲击改性超韧100,ST,中-高韧性500,MT,增韧改性500,T,UV,稳定 标准,UV,稳定107507超高,UV,稳定性127,UV527 UV927 UV,1727 UV,Glass -,高刚性填充570增强510,GR, 525 GR,抗静电等级增强,300,AS,增韧,300,AT,低磨损,Teflon,PTFE Fibers100 AF500 AFTeflon,PTFE Micropowder500 TL510 MP, 520 MP,Kevlar,Aramid Resin,100 KM,Internal Chemical500 CL,900 SP,500 AL,911 AL,Delrin,的主要应用,Gears,齿轮,Conveyors,传送带,Small wheels,小轮,Clips & snap-fits,夹子、扣具,Springs,弹簧,Bearings,轴承,Aerosol valves,喷雾阀,Video tape reels,磁带卷,Ski bindings,滑雪板紧固件,Lighters,打火机,Pumps,水泵,Zippers and buckles,拉链,Irrigation systems,灌溉系统,Kitchen appliances,厨房用具,Office automation equipment components,OA,自动化设备部件,Fuel system components,燃油系统,Safety system components, seat belt parts,安全系统，安全带扣,Clips, fasteners, control switches,扣具、紧固件开关,Door handle, door systems components,门把手,Window guides,窗户导架,Loudspeaker grilles,扬声器格栅,Heavy load-bearing gears insmall motors (window lifts,seat adjusters, wipers),重负荷齿轮,Interior, color-matched trim,有颜色要求内部饰件,Delrin,在汽车中的应用,Rynite,PET,热塑性饱和聚酯,Rynite,PET,是杜邦公司生产的热塑性饱和聚酯材料的注册商标.,Rynite,PET,所能提供的等级均为玻纤/矿物改性等级.,OO,ll,ll,C,C,O,C,H,2,C,H,2,O,n,PET,饱和聚酯 性能,优势:,刚性,冲击强度,高温下的尺寸稳定性. (155/200,C),高温下的颜色稳定性,耐,UV,性能,抗蠕变性,阻燃性,电绝缘性突出 (,class F),表面光泽好,易着色,局限性:,长期在水中的使用温度 70 ,C,度的水中的长期使用性,耐酸及醇等化学品,缺口敏感性,常用于替代:,金属 (重量,腐蚀),尼龙 (尺寸稳定性),聚甲醛 (耐温性),PBT 的改性手段,冲击改性,阻燃,无定形聚合物,增强 玻纤 矿物,Crastin,PBT ,标准规格,TypeModificationProduct,非增强标准等级,S600F10,流动性好,S610,超韧,ST820,玻纤增强15%,GlassSK60220% GlassSK60330% GlassSK60545% GlassSK608,无增强的标准等级,S660FR,阻燃改性超韧,ST830FR,玻纤增强的15%,GlassSK652FR1,阻燃等级30%,GlassSK655FR1,Crastin,PBT ,特殊规格产品,FeatureModificationProduct,抗水解15%,GlassHR5015F,等级30%,GlassHR5030F,高流动15%,GlassHF672FR,的阻燃等级30%,GlassHF675FR,低翘曲40%,G/MLW617 30% G/M - FRLW685FR,低比重的低20%,GlassLW9320,翘曲等级30%,GlassLW9330 20% Glass - FRLW9320FR30% Glass - FRLW9330FR,Connectors,连接器,Relays and switches,继电器、轻触开关,Small electrical motors,小马达,Lamp sockets,灯座,Spotlights,照明灯,Crastin,PBT,的主要应用,Consumer,Goods,消费品,Furniture,knobs,家具旋钮把手,Oven,knobs,烤箱旋钮把手,Housings and,covers,电器外壳及盖子,Brackets,托架,Crastin,PBT,在汽车中的应用,Clips and fasteners,扣件、紧固件,Electrical connectors,电子连接器,Ignition system parts,点火装置,Small electrical motors,小马达,Exterior door handles,外门把手,Head lamp reflectors,前大灯反射罩,Zenite,LCP,Zenite,又名,L,iquid,C,rystal,P,olymer (LCP),即液晶聚合物.,它是一种各向异性的,强度极高的芳香族聚酯类产品, 具有很高的结晶性.,LCP,的性能,优势:,是刚性, 韧性和强度的完美结合,低吸湿性,尺寸稳定性,使用温度高,耐辐射性好,出色的耐化学性,天生具有阻燃性,低的线形热膨胀系数,局限性:,熔接痕强度差,杜邦生产的,Zenite,LCP,树脂的性能,优势:,高流动, 成型加工性好,独特的高,HDT,和出色韧性的结合,低吸湿性,尺寸稳定性好,高使用温度 (,UL electrical RTI 240C),高耐辐射性,出色的耐化学性,天生具有阻燃性,低线形热膨胀系数,回料允许使用比例高,常用于替代:,其他的,LCP:,更短的生产周期 更好的流动 更高的,HDT,陶瓷 (重量, 韧性),PPS,热固性材料,Zenite,LCP ,标准等级,GlassMineralreinforcedreinforcedHDTType%CZenite,通用级30 2606130,L402726140L,矿物增强302406330,耐高温302907130452957145,L,玻纤/矿物混合10203224,L10303226L,低成本302273130,L,248,高性能热塑性工程塑料概述,Zenite,LCP,100,125,150,175,200,225,250,200,250,300,PA66,PET,PBT,Zytel,HTN,PPS,UL Relative Temperature Index, C,Heat Deflection Temperature at 1.8 MPa, C,不同压力下的蛇形流动测试,Zenite,7130,Zenite,6130,Xydar,G330,Vectra,A130,Vectra,E130,Vectra,C130,Xydar,G540,Xydar,G930,28,MPa,90,MPa,Vectra,is a registered trademark of Ticona. Xydar,is a registered trademark of Amoco.,E/E Industry,Connectors,连接器,Lamp sockets,灯座,Coil bobbins,线圈骨架,Electrical motors,马达,Fiber optic connectors,光纤连接器,Fuses,保险丝,Circuit board components,电路板组件,Zenite,LCP,的主要应用,Automotive:,Sensors,传感器,Coil bobbins,线圈骨架,Components to:,Ignition,systems,点火系统, Pumps,泵体,Power,train,传动件,Hytrel,热塑性聚酯弹性体,Hytrel,是一种热塑性,醚-酯,类弹性体,综合具有橡胶和塑料的性能.,易于按照常用的塑料的加工方法进行成型, 如注塑, 挤出, 吹塑等.,Hytrel, :,t,hermoplastic-,e,ther-,e,ster,e,lastomer,A tailor-made molecule that fits your needs,Hytrel,TPEE ( TEEE),(,polyester),Hard segment,(,polyether),Soft segment,From Shore D30,flexural modulus,4,000,psi,flexural modulus,To Shore D82,175,000,psi,TPE,的性能,优势:,弥补了橡胶和刚性的工程塑料之间的空缺,Offering with broad range of physical properties,Processing versatility & ease,Post processing ease,高冲击强度,出色的抗疲劳性,使用温度范围广,出色的耐有机溶剂性,局限性:,耐,UV,性,耐极性溶剂,耐划伤性小,常用于替代:,橡胶(易于成型, 回收使用, 系统成本低, 更好的性能),TPU (,成型加工更容易),Metals (,部件一体化设计),Properties, Features & Benefits,在很宽的温度范围内具有优异的抗弯曲性,可以通过合适的韧性、回弹性、冲击特性进行能量消耗监控,耐化性优异,可以像大部分热塑性塑料一样进行加工,可简单加工不同厚度的产品,不含增塑剂,产品种类,TypeProducts,通用级,G3548W/G3548LG4774/ G4778 G4074/ G4078WG5544,高性能40565556 等级406963564556724655268238,特殊等级3078,HTR6108 HTR4275BKHTR5612BKHTR8139LV5555HSHTR8068,母料10,MSmoisture stabilizer (,用于产品20,UVUV stabilizer,性能改进)30,HSheat stabilizer40CBcarbon black (UV screen)51FR & 52FRflame retardant,产品种类,用于特殊用途的产品 (,Compounded Grades),ApplicationGrade,Air Bag DeploymentDYM100BKDYM600BK Doors (ABDD)DYM160BKDYM830BK DYM350BKDYM1300BKDYM500BK,Constant Velocity JointHTR4275BK HTR8139LV (CVJ) Boots /HTR5612BK HTR8139BK Blow Moldable: HTR8105BK HTR8223BK HTR8136BK,Hytrel,市场定位:汽车,Air Bag Deployment Doors (ABDD),(broad use temperature range,ductile at low temperature,combination of properties andprocessing, and post processing ease),Constant Velocity Joint (CVJ) Boots,(broad use temperature range,blow moldable, excellent abrasion,flex fatigue resistance and grease resistance),Air Intake Ducts,进气导管,(blow moldable, component integration ease),Hytrel,市场定位:汽车,防尘罩,(grease resistance),饰带,(broad use temperature range, ductile at low temperature, energy absorption, paintable),齿轮,(noise dampening, energy absorption),水汽防御盖,(excellent hydrocarbon fluid resistance),汽车电缆,(chemical resistance, high temperature resistance, electrical insulation),Hytrel,市场定位:非汽车,软管和门管,(broad use temperature range, low temperature flexibility, hydraulic fuel resistance),电线电缆, Fiber Optic,Ocean,Cable,(optical insulation, ease of processing),能量消耗监控,(energy absorption, memory),鞋类,(bashore resilience, hysterisis),呼吸系统过滤膜,(high MVTR, monolythic, viral/bacterial barrier),配色产品,杜邦工程塑料产品的主要特性概述,Delrin,润滑性,无须增强即具有,高刚性,Zytel,高强度, 韧性,耐化学性和耐热性,Hytrel,设计上自由度大,抗疲劳性好,Vespel, extreme wear resistance, parts & shapes,Zenite,流动性好,使用温度高,Rynite,高刚性,电性能好,用工程塑料首选杜邦,Crastin,易于成型加工,尺寸稳定性好,Registered trade name of DuPont,