经典化学反应500个

1 Acetoacetic Ester Condensation 2 Acetoacetic Ester Syntheses 3 Acyloin Condensation 4 Adkins Catalyst 5 Adkins-Peterson Reaction 6 Akabori Amino Acid Reactions 7 Alder-Rickert Rule 8 Aldol-Condensation 9 Algar-Flynn-Olyamada(AFO)Reaction 10 Allan-Robinson Reaction 11 Allylic Rearrangement 12 Amadori Rearrangement 13 Andrussov Oxidation 14 Arens-van Dorp Synthesis; Isler Modification 15 Arndt-Eistert Synthesis 16 Auwers Synthesis 17 Aza-Claisen Rearrangemment 18 Baeyer-Drewson Indigo Synthesis 19 Baeyer-Villiger Rearrangement 20 Bakeland(Bakelite)Process 21 Baker-Venkataraman Transformation 22 Bally-Scholl Synthesis 23 Bamberger Rearrangement 24 Bamberger Triazine Synthesis 25 Bamford-Stevens Reaction 26 Barbier Reaction 27 Barbier-Wieland Degradation 28 Bardhan-Sengupta Phenanthrene Synthesis 29 Bart Reaction (Scheller Modification 30 Barton Deoxygenation (Barton-McCombie Reaction) 31 Barton Olefin Synthesis (Barton-Kellogg Reaction) 32 Barton Reaction 33 Baudisch Reaction 34 Baylis-Hillman Reaction 35 Bechamp Reaction 36 Beckmann Rearrangement 37 Benary Reaction 38 Benkeser Reduction 39 Benzidine Rearrangement; Semidine Rearrangement 40 Benzilic Acid Rearrangement 41 Benzoin Condensation 42 Bergman Reaction 43 Bergmann Azlactone Peptide Synthesis 44 Bergmann Degradation 45 Bergamann-Zevars Carbobenzoxy Method 46 Bernthsen Acridine Synthesis 47 Betti Reaction 48 Biginelli Pyrimidine Syntheis 49 Birch Reduction 50 Bischler-M鰄lau Indole Synthesis 51 Bischler-Napieralski Reaction. 52 Bischler-Triazine Synthesis 53 Blaise Ketone Synthesis 54 Blaise Reaction 55 Blanc(Chloromethylation ) Reaction 56 Blanc Reaction(Blanc Rule) 57 Bodroux-Chichibabin Aldehyde Synthesis 58 Bodroux Reaction 59 Bogert-Cook Synthesis 60 Bohn-Schmidt Reaction 61 Boord Olefin Synthesis 62 Borsche-Drechsel Cyclization. 63 Bosch-Meiser Urea Process 64 Bouveault Aldehyde Synthesis 65 Bouveault-Blanc Reduction 66 Boyland-Sims Oxidation 67 Bradsher Cyclization(Bradsher Cycloaddition) 68 Bradsher Reaction 69 Brook Rearrangement 70 Bucherer-Bergs Reaction 71 Bucherer Carbazole Synthesis 72 Bucherer Reaction 73 Buchner-Curtius-Schlotterbeck Reaction. 74 Buchner Method of Ring Enlargement 75 Buchwald-Hartwig Cross Coupling Reaction 76 Camps Quinoline Synthesis 77 Cannizzaro Reaction 78 Carroll Rearrangement 79 Castro-Stephens Coupling(Castro Reaction,Stephens-Castro Coupling) 80 Chapman Rearrangement 81 Chichibabin Pyridine Synthesis 82 Chichibabin Reaction 83 Chugaev Method 84 Chugaev Reaction (Tshugaeff Olefin Synthesis) 85 Ciamician-Dennstedt Rearrangement 86 Claisen Condensation 87 Claisen Rearrangement 88 Claisen-Schmidt Condensation 89 Clemmensen Reaction 90 Combes Quinoline Synthesis. 91 Conrad-Limpach Synthesis 92 Cope Elimination Reaction 93 Cope Rearrangement 94 Corey-Bakshi-Shibata Reduction(CBS) 95 Corey-House Synthesis 96 Corey-Kim Oxidation 97 Corey-Winter Olefin Synthesis 98 Cornforth Rearrangement 99 Craig Method 100 Criegee Reaction 101 Crams Rule of Asymmetric Induction 102 Creighton Process 103 Criegee Reaction 104 Crum Brown-Gibson Rule 105 Curtius Rearrangement (Curtius Reaction) 106 Dakin Reaction 107 Dakin-West Reaction 108 Darapsky Degradation 109 Darzens Condensation (Darzens-Claisen Reaction; Glycidic Ester Condensation) 110 Darzens Procedure 111 Darzens Synthesis of Tetralin Derivatives 112 Darzens-Nenitzescu Synthesis of Ketones 113 Delepine Reactions 114 Demjanov Rearrangement 115 Dess-Martin Oxidation 116 de Mayo Reaction 117 D-Homo Rearrangement of Steroids 118 Dieckmann Reaction 119 Diels Alder Reaction 120 Diels Reese Reaction 121 Dienol Benzene Rearrangement 122 Dienone-Phenol Rearrangement 123 Dimroth Rearrangement 124 Doebner Reaction 125 Doebner-Miller Synthesis (Beyer Method for Quinolines). 126 Doering-LaFlamme Carbon Chain Extension 127 Dotz Reaction 128 Dowd-Beckwith Ring Expansion Reaction 129 Duff Reaction 130 Dutt-Wormall Reaction 131 Eastwood Reaction (Eastwood Deoxygenation) 132 Eder Reaction 133 Edman Degradation 134 Ehrlich-Sachs Reaction 135 Einhorn-Brunner Reaction 136 Elbs Persulfate Oxidation 137 Elbs Reaction 138 Eltekoff Reaction 139 Emde Degradation 140 Emmert Reaction 141 Ene Reaction ( Alder-Ene Reaction) 142 Erlenmeyer-Plochl Azlactone and Amino Acid Synthesis 143 Eschenmoser Fragmentation 144 图片链接 145 Eschweiler-Clarke Reaction. 146 Etard Reaction 147 Favorskii-Babayan Synthesis. 148 Favorskii Rearrangement 149 Feist-Benary Synthesis 150 Fenton Reaction 151 Ferrario Reaction 152 Fickelstein Reaction 153 Fischer-Hepp Rearrangement 154 Fischer Indole Synthesis 155 Fischer Oxazole Synthesis 156 Fischer Peptide Synthesis 157 Fischer Phenylhydrazine Reaction 158 Fischer Phenylhydrazone and Oxazone Reaction 159 Fischer-Speier Esterification Method 160 Flood Reaction 161 Forster-Decker Method 162 Forster Reaction 163 Franchimont Reaction 164 Frankland-Duppa Reaction 165 Frankland Synthesis 166 Freund Reaction 167 Friedel-Crafts Reaction 168 Friedlaender Synthesis 169 Fries Rearrangement 170 Fritsch-Buttenberg-Wischell Rearrangement 171 Fujimoto-Belleau Reaction 172 Gabriel-Coleman Rearrangement(Gabriel Isoquinoline Synthesis) 173 Gabriel Ethylenimine Method 174 Gabriel Synthesis 175 Gallagher-Hollander Degradation 176 Gastaldi Synthesis 177 Gattermann Aldehyde Synthesis 178 Gattermann-Koch Reaction 179 Gattermann-Skita Synthesis 180 Gibbs Phthalic Anhydride Process 181 Glaser Coupling 182 Gogte Synthesis 183 Goldschmidt Process 184 Gomberg-Bachmann-Hey Reaction 185 Gomberg-Free Radical Reaction 186 Gould-Jacobs Reaction 187 Graebe-Ullmann Synthesis 188 Griess Diazo Reaction; Witt and KnoevenagelDiazotization Methods 189 Grignard Degradation 190 Grignard Reaction 191 Grundmann Aldehyde Synthesis 192 Gryszkiewicz-Trochimowski and McCombie Method. 193 Guareschi-Thorpe Condensation 194 Guerbet Reaction 195 Gutknecht Pyrazine Synthesis. 196 Haller-Bauer Reaction 197 Hammick Picolinic Acid Decarboxylation (Hammick Reaction). 198 Hantzsch Pyridine Synthesis;Gattermann-Skita Synthesis;Guareschi-Thorpe Condens.;Knoevenagel-Fries Modification 199 Hantzch Pyrrole Synthesis 200 Harries Ozonide Reaction 201 Haworth Methylation 202 Haworth Phenanthrene Synthesis. 203 Hayashi Rearrangement 204 Helferich Method 205 Heck Reaction 206 Hell-Vollard-Zelinsky Halogenation 207 Henkel Reaction(Raecke process,Henkel process 208 Henry Reaction;Kamlet Reaction 209 Herz Reaction; Herz Compounds 210 Herzig-Meyer Alkimide Group Determination 211 Heumann Indigo Synthesis 212 Hilbert-Johnson Reaction 213 Hinsberg Oxindole and Oxiquinoline Synthesis 214 Hinsberg Reaction 215 Hinsberg Sulfone Synthesis 216 Hinsberg Synthesis of Thiophene Derivatives 217 Hoch-Campbell Ethylenimine Synthesis 218 Hofmann Degradation(Exhaustive Methylation 219 Hofmann Isonitrile Synthesis (Carbylamine Reaction). 220 Hofmann-Loffler Reaction (Loffler-Freytag Reaction) 221 Hofmann-Martius Rearrangement 222 Hofmann Reaction (Hofmann Rearrangement) 223 Hofmann Rule 224 Hofmann-Sand Reactions 225 Hooker Reaction 226 Houben-Fischer Synthesis 227 Houben-Hoesch Reaction 228 Hunsdiecker Reaction(Borodine Reaction) 229 Hydroboration Reaction 230 Ivanov(Ivanoff) Reagent 231 Jacobsen Epoxidation 232 Jacobsen Rearrangement 233 Janovsky Reaction 234 Japp-Klingemann Reaction 235 Jones Oxidation 236 Jourdan-Ullmann-Goldberg Synthesis 237 Julia Olefination (Julia-Lythgoe Olefination) 238 Kendall-Mattox Reaction 239 Kiliani-Fischer Synthesis 240 Kishner Cyclopropane Synthesis 241 Knoevenagel Condensation 242 Knoop-Oesterlin Amino Acid Synthesis 243 Knorr Pyrazole Synthesis 244 Knorr Pyrrole Synthesis 245 Knorr Quinoline Synthesis 246 Koch-Haaf Carboxylations 247 Kochi Reaction 248 Koenigs-Knorr Synthesis 249 Kolbe Electrolytic Synthesis 250 Kolbe-Schmitt Reaction 251 Kondakov Rule 252 Kostanecki Acylation 253 Krafft Degradation 254 Krapcho Decarbaloxylation 255 Krohnke Aldehyde Synthesis 256 Krohnke Pyridine Synthesis 257 Kucherov Reaction 258 Kuhn-Winterstein Reaction. 259 Ladenburg Rearrangement 260 Lebedev Process 261 Lehmstedt-Tanasescu Reaction 262 Letts Nitrile Synthesis 263 Leuckert Amide Synthesis 264 Leuckart(Leukart) Reaction 265 Leuckart Thiophenol Reaction 266 Leuckart-Wallach Reaction 267 Levinstein Process 268 Lieben Iodoform Reaction (Haloform Reaction) 269 Lobry de Bruyn-van Ekenstein Transformation. 270 Lossen Rearrangement 271 McFadyen-Stevens Reaction. 272 McLafferty Rearrangement 273 Madelung Synthesis 274 Malaprade Reaction (Periodic Acid Oxidation) 275 Malonic Ester Synthesis 276 Mannich Reaction 277 McMurry Reaction 278 Merckwald Asymmetric Synthesis 279 Marschalk Reaction 280 Markownikoff Rule 281 Martinet Dioxindole Synthesis 282 ter Meer Reaction 283 Meerwein Arylation 284 Meerwein-Ponndorf-Verley Reduction; 285 Meisenheimer Rearrangements 286 Meldrum Acid 287 Menshutkin Reaction 288 Mentzer Pyrone Synthesis 289 Merrifield Solid-Phase Peptide Synthesis (SPPS) 290 Meyer and Hartmann Reaction 291 Meyer Reaction 292 Meyer-Schuster Rearrangement; Rupe Reaction 293 Meyer Synthesis ( Victor Meyer Synthesis) 294 Meyers Aldehyde Synthesis 295 Michael Reaction (Condensation, Addition) 296 Michaelis-Arbuzov Reaction 297 Miescher Degradation 298 Mignonac Reaction 299 Milas Hydroxylation of Olefins 300 Mislow-Evans Rearrangement 301 Mitsunobu Reaction 302 Moore Myers Cyclization 303 Mukaiyama Aldol Reaction 304 Mukaiyama-Michael Reaction 305 Nagata Hydrocyanation 306 图片链接 307 Nametkin Rearrangement 308 Nazarov Cyclization Reaction 309 Neber Rearrangement 310 Nef Reaction 311 Nef Synthesis 312 Negishi Cross Coupling 313 Nenitzescu Indole Synthesis 314 Nenitzescu Reductive Acylation 315 Nicholas Reaction 316 Niementowski Quinazoline Reaction 317 Niementowski Quinoline Synthesis 318 Nierenstein Reaction 319 Normant Reagents 320 Norrish Type Cleavage 321 Noyori Hydrogenation 322 Nozaki-Hiyama Coupling Reaction (Nozaki-Hiyama-Kishi Reaction) 323 Olefin Metathesis 324 Oppenauer Oxidation 325 Ostromyslenskii(Ostromisslenskii)Reaction 326 Overman Rearrangement 327 Paal-Knorr Pyrrole Synthesis 328 Paneth Technique 329 Parham Cyclization 330 Paolini Reaction 331 Passerini Reaction 332 Paterno-B點hi Reaction 333 Pauson-Khand Reaction 334 Payne Rearrangement 335 Pechmann Condensation 336 Pechmann Pyrazole Synthesis 337 Pellizzari Reaction 338 Pelouze Synthesis 339 Perkin Alicyclic Synthesis 340 Perkin Reaction 341 Perkin Rearrangement (Coumarin桞enzofuran Ring Contraction). 342 Perkow Reaction 343 Peterson Reaction (Olefination) 344 Petrenko-Kritschenko Piperidone Synthesis 345 Pfau-Plattner Azulene Synthesis 346 Pfitzinger Reaction 347 Pfitzner-Moffatt Oxidation (Moffatt Oxidation) 348 Pictet-Gams Isoquinoline Synthesis 349 Pictet-Hubert Reaction 350 Pictet-Spengler Isoquinoline Synthesis 351 Piloty Alloxazine Synthesis 352 Piloty-Robinson Pyrrole Synthesis 353 Pinacol Coupling Reaction 354 Pinacol Rearrangement 355 Pinner Amidine Synthesis 356 Pinner Method for Ortho Esters 357 Pinner Triazine Synthesis 358 Piria Reaction 359 Polonovski Reaction 360 Pomeranz-Fritsch Reaction (Schlittler-M黮ler Modification) 361 Ponzio Reaction 362 Pr関ost Reaction 363 Prilezhaev (Prileschajew) Reaction 364 Prins Reaction 365 Pschorr Reaction (Pschorr Synthesis) 366 Pummerer Reaction 367 Purdie (Irvine-Purdie) Methylation 368 Quelet Reaction 369 Ramberg-B鋍klund Reaction 370 Rap-Stoermer Condensation 371 Salol Reaction 372 Raschig Phenol Process 373 Reed Reaction 374 Reformatsky (Reformatskii) Reaction. 375 Reilly-Hickinbottom Rearrangement 376 Reimer-Tiemann Reaction 377 Reissert Indole Synthesis 378 Reissert Reaction (Reissert Compounds 379 Reppe Chemistry 380 Retro-Diels-Alder Reaction 381 Retropinacol Rearrangement 382 Reverdin Reaction 383 Riehm Quinoline Synthesis 384 Riemschneider Thiocarbamate Synthesis 385 Riley Oxidations (Selenium Dioxide Oxidation) 386 Ritter Reaction 387 Robinson Annelation Reaction 388 Robinson-Sch鰌f Reaction 389 Rosenmund von Braun Synthesis 390 Rosenmund Reaction(Arsonic Acids) 391 Rosenmund Reduction 392 Rothemund Reaction 393 Rowe Rearrangement 394 Rubottom Oxidation 395 Ruff-Fenton Degradation 396 Ruzicka Large Ring Synthesis 397 Saegusa Oxidation 398 Sakurai Reaction (Hosomi-Sakurai Reaction) 399 Salol Reaction 400 Sandmeyer Diphenylurea Isatin Synthesis 401 Sandmeyer Isonitrosoacetanilide Isatin Synthesis 402 Sandmeyer Reaction 403 Sarett Oxidation 404 Saytzeff Rule 405 Schiemann Reaction 406 Schiff Reaction(Schiff Bases) 407 Schmidlin Ketene Synthesis 408 Schmidt Reaction 409 Scholl Reaction 410 Schorigin (Shorygin) Reaction; Wanklyn Reaction 411 Sch鰈lkopf Bis-Lactim Amino Acid Synthesis 412 Schotten Baumann Reaction 413 Semmler-Wolff Reaction (Wolff-Semmler Aromatization, Woff Aromatization) 414 Serini Reaction 415 Sharpless Dihyroxylation 416 Sharpless Epoxidation 417 Sharpless Oxyamination 418 Simmons-Smith Reaction 419 Simonini Reaction 420 Simonis Chromone Cyclization 421 Skraup Reaction 422 Smiles Rearrangement 423 Sommelet Reaction 424 Sommelet Rearrangement 425 Sonn-Muller Method 426 Sorenson Formol Titration 427 Staedel-Rugheimer Pyrazine Synthesis. 428 Staudinger Reaction 429 Stephen Aldehyde Synthesis 430 Stevens Rearrangement 431 Stieglitz Rearrangement 432 Stille Coupling 433 Stobbe Condensation 434 Stoll? Synthesis 435 Stork Enamine Alkylation and Acylation 436 Strecker Amino Acid Synthesis 437 Strecker Degradation 438 Strecker Sulfite Alkylation 439 Stuffer Disulfone Hydrolysis Rule 440 Suarez Reaction(Suarez Fragmentation) 441 Sugasawa Reaction 442 Suzuki Coupling 443 Swarts Reaction 444 Swern Oxidation 445 Tafel Rearrangement 446 Tebbe Olefination(Methylenation) 447 Thiele Reaction(Thiele-Winter Acetoxylation) 448 Thorpe Reaction 449 Tiemann Rearrangement 450 Tiffeneau Reaction (Ring Enlargement) 451 Tishchenko Reaction (Tischischenko-Claisen Reaction) 452 Tollens Reagent 453 Traube Purine Synthesis 454 Trost Allylation ( Tsuji-Trost Reaction) 455 Trost Desymmetrization 456 Truce-Smiles Rearrangement 457 Tscherniac-Einhorn Reaction 458 Twitchell Process 459 Tyrer Sulfonation Process 460 Ugi Reaction (Four component condensation , 4CC) 461 Ullmann Reaction 462 Urech Cyanohydrin Method 463 Urech Hydantoin Synthesis 464 Van Slyke Determination 465 Varrentrapp Reaction 466 Vilsmeier-Haack Reaction 467 Voight Amination 468 Volhard-Erdmann Cyclization 469 von Braun Amide Degradation 470 von Braun Degradations; von Braun Cyanogen Bromide Reaction 471 von Richter Reaction(Rearrangement) 472 von Richter (Cinnoline) Synthesis 473 Vorbr黦gen Glycosylation 474 Wacker Oxidation 475 Wagner-Jauregg Reaction 476 Wagner-Meerwein Rearrangement 477 Walden Inversion 478 Wallach Rearrangement 479 Weerman Degradation 480 Weiss Reaction 481 Wenker Ring Closure 482 Wessely-Moser Rearrangement 483 Westphalen-Lettr? Rearrangement 484 Wharton Reaction 485 Whiting Reaction 486 Wichterle Reaction 487 Widman-Stoermer Synthesis 488 Willgerodt-Kindler Reaction 489 Williamson Synthesis 490 Wittig Reaction 491 1,2Wittig Rearrangement 492 2,3 Wittig Rearrangement 493 Wohl-Aue Reaction 494 Wohl Degradation 495 Wohl-Ziegler Reaction 496 Wohler Synthesis 497 Wolff-Kishner Reduction 498 Wolff Rearrangement 499 Wolffenstein-Boters Reaction 500 Woodward cis-Hydroxylation 501 Wurtz-Fittig Reaction 502 Wurtz Reaction 503 Zeisel Determination 504 Zerevitinov (Zerewitinoff) Determination 505 Ziegler Method (Thorpe-Ziegler Method) 506 Zimmermann Reaction 507 Zincke Disulfide Cleavage 508 Zinke Nitration 509 Zinke-Suhl Reaction