赢创德固赛在农药剂型SC,OD,EW研发新进展

,Titelmasterformat durch Klicken bearbeiten,Textmasterformate durch Klicken bearbeiten,Zweite Ebene,Dritte Ebene,Vierte Ebene,Fnfte Ebene,Page|,*,Titelmasterformat durch Klicken bearbeiten,Textmasterformate durch Klicken bearbeiten,Zweite Ebene,Dritte Ebene,Vierte Ebene,Fnfte Ebene,September 2007,|Business Presentation,Page|,*,Titelmasterformat durch Klicken bearbeiten,Textmasterformate durch Klicken bearbeiten,Zweite Ebene,Dritte Ebene,Vierte Ebene,Fnfte Ebene,Page|,*,Titelmasterformat durch Klicken bearbeiten,Textmasterformate durch Klicken bearbeiten,Zweite Ebene,Dritte Ebene,Vierte Ebene,Fnfte Ebene,September 2007,|Business Presentation,Page|,*,Titelmasterformat durch Klicken bearbeiten,Textmasterformate durch Klicken bearbeiten,Zweite Ebene,Dritte Ebene,Vierte Ebene,Fnfte Ebene,September 2007,|Business Presentation,Page|,*,Titelmasterformat durch Klicken bearbeiten,Textmasterformate durch Klicken bearbeiten,Zweite Ebene,Dritte Ebene,Vierte Ebene,Fnfte Ebene,September 2007,|Business Presentation,Page|,*,赢创德固赛在农药剂型,SC,OD,EW,研发新进展,SC,OD,EW,formulation,development,Evonik,Degussa,Shanghai,赢创德固赛（中国）投资有限公司,袁永新 胡圣豪,20100816,Page|,2,solid formulation,固体制剂,SG,，,WP,，,SP,，,WDG,liquid formulation,液体制剂,SL,，,ME,，,EC,，,EW,，,SC,，,CS,Formulation,type,and,treand,制剂类型及发展方向,Page|,3,Ratio of,formulation,in,china,国内剂型比例制剂类型及发展方向,EC,乳油,26%,WP,可湿性粉剂,10%,SC,悬浮剂,16%,SL,水剂,19%,WDG,水分散粒剂,12%,Others,其它,12%,EW,水乳剂,5%,Page|,4,Suspension,concentration,(,水悬浮剂）,SC TG is milled finely and suspended in the water with dispersing agent,wetting agent,thickner,adjuvant,是将固体原药磨细以后，悬浮于含有分散剂，润湿剂，增稠剂，增效剂的水中。,Advantages:,No solvent,没有溶剂。,Can contain high concentrations of,ai,高含量。,Easy to measure and mix,容易称量混合。,Compatible with aqueous concentrates,与水剂型制剂兼容。,Disadvantages:,Difficult to produce successfully,研发难度大。,Can settle out in storage,贮存中沉淀。,Sensitive to freezing,不耐冻。,Sensitive to,ai,purity and polymorphic form,对原药杂质和晶体免感。,Page|,5,Suspension,concentration,水悬浮剂,Component,Typical Amount,%,w/w,Active Ingredient,（原药）,80,Wetter,（润湿剂,),1-2,Dispersant(,分散剂）,3-,6,Antifoam,（消泡剂）,0.5,Antifreeze,（防冻剂）,5-,20,Antisettling,agent,（抗沉降剂）,0.1,2,Biocide,（防腐剂）,0-0.2,Water,（水）,To volume,Page|,6,Dispersants,分散剂,Dispersants can give,steric,and electrostatic stabilization of fine solid particles,in water,分散剂可以通过空间位阻或者静电作用将细小颗粒悬浮在水中。,Dispersants can stop the process of aggregation and,crystallation,分散剂可以防止粒子的聚合和重结晶（奥式熟化）,Dispersants can reduce the milling viscosity,分散剂可以降低研磨粘度,Page|,7,Techincal,problem,in SC,development,SC,研发中的技术难题,Viscosity increase in milling,研磨时粘度增大,Solution,Add more dispersants,增加更多 的 分散剂,Change dispersants,改变分散剂,Use the combination of different sorts of dispersants,使用不同种类的分散剂组合,Page|,8,Techincal,problem,in SC,development,SC,研发中的技术难题,Foam in milling,研磨中泡沫多,Solution,解决方案,Change antifoam,改变消泡剂,change wetter,改变润湿剂,Reduce the wetter,减少润湿剂,Change dispersants,改变分散剂,Page|,9,Technical,problem,in SC,development,SC,研发中的技术难题,Particle,increase,in,storage,粒径在贮存中增加,Aggrecation,of,particle,粒径絮凝,Solution,解决方案,Change,the,dispersants,改变分散剂,Add more dispersants,增加分散剂用量,Use,combination,of d,is,persants,使用分散剂组合,Add,some,structure,agent,加些结构剂,Page|,10,Fungicide alone,单用杀菌剂,Pesticide droplet on surface of leaf,喷雾液呈水珠状，不能润湿菌丝,Techincal,problem,in SC,development,SC,研发中的技术难题,Particle,increase,in,storage,在贮存中粒径增大,Crystallation,of,particle,粒径的重结晶,Solution,解决方案,Use,combination,of,dsiperants,使用分散剂组合,Use,dispersants,with,high CMC,使用具有高,CMC,的分散剂,Use,comb,polymeric,surfactant,使用 梳妆聚合物分散剂,Add,some,inogranic,salt,加一些无机盐,Add,some,water,soluble,polymer,with,high,moleculer,weight,加 水溶性高分子量高聚物,Page|,11,Imidacloprid,SC 600formulation,吡虫啉产品介绍,具有时代特质的划时代杀虫剂,-,吡虫啉,1.,结构独特，高效，低毒，低残留的特异性烟碱类杀虫剂,2.,杀虫镨广，适用作物多，用量少，持久期长，应用安全，环境友好。,3.,作用机理；胃毒，触杀，内吸,应用现状及前景,仍将是主要应用的杀虫剂,合理的剂型选择很重要,水悬浮剂,水分散粒剂,Page|,12,Imidacloprid,SC 600formulation,吡虫啉,600g/L,配方组成,Guideline Formulation,Imidacloprid,Water,PG,BREAK-THRU DA 646,BREAK-THRU DA 675,Thickener,Biocide,600g/L,吡虫啉,SC,600,吡虫啉研磨相入水效果,Page|,13,SC,Stability,Test,Using,Lumifuge,悬浮剂稳定性的评测方法,Unstable,Stable with BREAK-THRU,Page|,14,Imidacloprid,SC 600formulation,吡虫啉,600g/L,配方评价,Item,项目,Suspensibility,悬浮率,Particle size,粒径,(D50),Viscosity,粘度,Separation and sediment,分层 和沉淀,RT,98%,5.8,450,no separation no sedimentation,（不析水 不沉降）,HT,98%,6.0,380,Little separation,No sedimentation,（少量析水，没有沉淀）,Analysis the formulation by storage in 54C for 28days,热贮,28,天,54C,下的情况,Page|,15,Particle size analysis,Imidacloprid,SC 600formulation,吡虫啉,600g/L,Page|,16,Particle size analysis,Imidacloprid,SC 600formulation,吡虫啉,600g/L,20%Pyridaben SC,formulation,20%,哒螨灵 配方组成,Guideline Formulation,Pyridaben,PG,BREAK-THRU DA 646,BREAK-THRU DA 655,Thickener,Biocide,Water,Page|,18,BREAK-THRU,Product,DA,Series,for,In-Can,Formulations,/,赢创德固赛公司,SC,配方助剂产品,BreakThru,DA 646,BreakThru,DA 655,BreakThru,DA 675,BreakThru,DA 752 W,BreakThru,AF 9903,Tego,Antifoam,32 H,Page|,19,BREAK-THRU,Product,DA,Series,for,In-Can,Formulations,/,赢创德固赛公司,SC,配方助剂产品,BreakThru,DA 646,Special poly,ether,（特殊的聚醚分散剂）,Reducing,of,milling,