资源描述
4 冶金过程物理化学4.1 冶金过程热力学冶金过程热力学thermodynamics of metallurgical processes统计热力学statistical thermodynamics不可逆过程热力学thermodynamics of irreversible processes化学热力学chemical thernodynamics表面热力学surface thermodynamics合金热力学thermodynamics of alloys冶金热力学数据库thermodynamics databank in metallurgy系system单元系single-componentsystem多元系multicomponent system均相系统homogeneous system广度性质extensive property强度性质intensive property过程process等温过程isothermal process等压过程isobaric process等容过程isochoric process绝热过程adiabatic process可逆过程reversible process不可逆过程irreversible process自发过程spontaneous process自理过程physical process化学过程chemical process冶金过程metallurgical process化学反应chemical reaction化合反应combination reaction分解反应decomposition reaction置换反应displacement reaction可逆反应reversible reaction不可逆反应irreversible reaction电化学反应electrochemical reaction多相反应multiphase reaction固态反应solid state reaction气一金(属)反应gas-metal reaction渣一金（属）反应slag-metal reaction平衡equilibrium化学平衡chemical equilibrium相平衡phase equilibrium热力学平衡thermodynamic equilibrium亚稳平衡metastable equilibrium热力学函数thermodynamic function偏摩尔量partial molar quantity总摩尔量integral molar quantity标准态standard state焓enthalpy生成焓enthalpy of formation反应焓enthalpy of reaction熵entropy吉布斯能Gibbs energy生成吉布斯能Gibbs energy of formation反应吉布斯能Gibbs energy of reaction溶解吉布斯能Gibbs energy of solution吉布斯能函数Gibbs energy function化学位chemical potential热化学thermochemistry热效应heat effect热容heat capacity熔化热heat of fusion汽化热heat of vaporization升华热heat of sublimation相变热heat of phase transformation放热反应exothermic reaction吸热反应endothermic reaction赫斯定律Hesss law相律phase rule相图phase diagram一元相图single-component phase diagram二元相图binary-component phase diagram三元相图ternary-component phase diagram液相线liquidus固相线solidus共晶点eutectic point杠杆规则lever rule溶液solution溶质solute溶剂solvent固溶体solid solution溶液浓度concentration of solution摩尔分数mole fraction冶金熔体metallurgical melt金属熔体metal melt(炉)渣,熔渣slag熔盐molten salt, fused salt理想溶液ideal solution真实溶液real solution正规溶液regular solution活度activity活度系数activity coefficient拉乌尔定律Raoults law亨利定律Henrys law纯物质标准态pure substance standard质量溶液标准(态)1 mass% solution standard无限稀溶液参考态reference state of infinityly dilute solution相互作用系数interaction coefficient化学反应等温式chemical reaction isotherm吉布斯亥姆霍兹方程Gibbs-Helmholtz equation质量作用定律law of mass action平衡常数equilibrium constant平衡值equilibrium value直接还原direct reduction间接还原indirect reduction金属热还原metallothermic reduction选择性氧化selective oxidation渣碱度basicity of slag光学破度optical basicity酸性氧化物acid oxide碱性氧化物basicoxide两性氧化物amphoteric泡沫渣foaming slag熔渣的分子理论molecular theory of slag熔渣的离子理论ionization theory of slag脱氧平衡deoxidation equilibrium脱氧常数deoxidation constant熔渣脱硫desulfurization by slag气态脱硫desulfurization in the gaseous state硫分配比sulfur partition ratio硫化物容量sulfide capacity氧化脱磷dephosphorization under oxidizing atmosphere磷分配比碳一氧平衡carbon-oxygen equilibrium真空脱碳vacuum decarburization去气degassing去除非金属夹杂(物)elimination of nonmetallic inclusion非金属夹杂(物)变形form modification of nonmetallic inclusion脱硅desiliconization脱锰demanganization分配平衡distribution law化学气相沉积chemical vapor deposition(CVD)4.2 冶金过程动力学微观动力学microkinetics化学动力学chemical kinetics反应途径reaction path反应机理reaction mechanism基元反应elementary reaction平行反应parallel链反应chain reaction总反应overall reaction反应速率reaction rate反应速率常数reaction rate constant反应级数reaction order零级反应zero order reaction一级反应first order reaction二级反应second order reactionn级反应nth order reaction碰撞理论collision theory活化能activation energy表现活化能apparent activation energy阿伦尼乌斯方程Arrhenius equation半衰期half-life宏观动力学macrokinetics冶金过程动力学kinetics of metallurgical process传输现象transport phenomena传质mass transfer传热heat transfer动量传输momentum transfer层流laminar flow湍流turbulent flow气泡gas bubble鼓泡bubbling射流jet液滴liquid droplet粘度viscosity边界层boundary layer流率flow rate通量flux扩散diffusion菲克第一扩散定律Ficks 1st law of diffusion菲克第一扩散定律Ficks 2nd law of diffusion扩散系数diffusion coefficient传质系数mass transfer coefficient热传导heat conduction热对流heat convection自然对流natural convection强制对流forced convection热辐射heat radiation导热率thermal conductivity传热系数heat transfer coefficient体内浓度bulk concentration未反应核模型unreacted core model扩散控制反应diffusion-controlled reaction化学控制反应chenical-controlled reaction混合控制反应mixed-controlled reaction相似原理priciple of similarity雷诺数Reynolds number固定床fiexed bed填充床packed bed移动床moving bed流态化床fluidized bed混合时间mixing time停留时间residence time, retention time催化catalysis催化剂catalyst表面能surface energy表面张力surface tension界面能interfacial energy界面张力interfacial tension润湿wetting表面活性物质surface-active substance吸收absorption吸附absorption4.3 冶金电化学冶金电化学metallurgical electrochemistry熔盐电化学electrochemistry of fused salts固态离子学solid state ionics电解质溶液electrolyte solution阳离子cation阴离子anion电导conductance电导率conductivity电阻resistance电极electrode阴极cathode阳极anode电镀electroplating固体电解质solid electrolyte稳定的氧化锆stablized zirconia氧传感器oxygen sensor硅传感器silicon sensor定氧测头oxygen probe定硅测头silicon probe4.4 冶金物理化学研究方法冶金物理化学研究方法research methods in metallurgical physicalchemistry热电偶thermocouple量热计calorimeter热太平thermobalance热分析thermal analysis差热分析differential thermal analysis,DTA热重法thermogravimetry分子筛molecular sieve5 钢铁冶金5.1 炼焦炼焦coking高温炭化high temperature carbonization塑性成焦机理plastic mechanism of coke formation中间相成焦机理mesophase mechanism of coke formation选煤coal preparation, coal washing配煤coal blending配煤试验coal blending test炼焦煤coking coal气煤gas coal肥煤fat coal瘦煤lean coal焦炉coke oven焦化室oven chamber焦饼coke cake结焦时间coking time周转时间cycle time装煤coal charging捣固装煤stamp charging推焦coke pushing焦炭熄火coke quenching干法熄焦dry quenching of coke焦台coke wharf装煤车larry car推焦机pushing machine拦焦机coke guide熄焦车quenching car焦炉焖炉banking for coke oven焦炭coke冶金焦metallurgical coke铸造焦foundry coke焦炭工业分析proximate analysis of coke焦炭元素分析ultimate analysis of coke焦炭落下指数shatter index of coke焦炭转鼓指数drum index of coke焦炭热强度hot strength of coke焦炭反应性coke reactivity焦炭反应后强度post-reaction strength of coke焦炭显微强度microstrength of coke焦炉煤气coke oven gas发热值calorific value煤焦油coal tar粗苯crude benzol苯benzene甲苯toluene二甲苯xylene苯并呋喃-茚树脂 coumarone-indene resin精萘refined naphthalene精蒽refined anthracene煤焦油沥青 coal tar pitch沥青焦pitch coke针状焦needle coke型焦formcoke5.2 耐火材料耐火材料refractory materials耐火粘土fireclay高岭土kaolin硬质粘土flint clay轻质粘土soft clay陶土pot clay蒙脱石montmorillonite叶蜡石pyrophyllite膨润土bentonite鳞石英tridymite方石英cristobalite砂岩sandstone耐火石firestone莫来石mullite氧化铝alumina烧结氧化铝sintered alumina电熔氧化铝fused alumina刚玉corundum红柱石andalusite蓝晶石kyanite,cyanite硅线石sillimanite橄榄石olivine方镁石periclase镁砂magnesia合成镁砂synthetic sintered magnesia电熔镁砂fused magnesia烧结白云石砂sintered dolomite clinker合成镁铬砂synthetic magnesia chromite clinker尖晶石spinel镁铬尖晶石magnesia chrome spinel,magnesiochromite硅藻土diatomaceous earth, infusorial earth蛭石vermiculite珍珠岩perlite碳化硅silicon carbide氮化硅silicon nitride氮化硼boron nitride粘土熟料chamotte熟料grog轻烧light burning,soft burning死烧dead burning,hard burning成型模注shaping moulding机压成型mechanical pressing等静压成型isostatic pressing摩擦压砖机friction press液压压砖机hydraulic press捣打成型ramming process熔铸成型fusion cast process砖坯强度green strength,dry strength隧道窑tunnel kiln回转窑rotary kiln倒焰窑down draught kiln耐火砖refractory brick标准型耐火砖standard size refractory brick泡砂石quartzite sandstone酸性耐火材料acid refractory material硅质耐火材料siliceous refractory material硅砖silica brick,dinas brick熔融石英制品fused quartz product硅酸铝质耐火材料aluminosillicate refractory半硅砖semisilica brick粘土砖fireclay brick,chamotte brick石墨粘土砖graphite clay brick高铝砖high alumina brick硅线石砖sillimanite brick莫来石砖mullite brick刚玉砖corundum brick铝铬砖alumina chrome brick熔铸砖fused cast brick碱性耐火材料basic refractory material镁质耐火材料magnesia refractory material镁砖magnesia brick镁铝砖magnesia alumina brick镁铬砖magnesia chrome brick镁炭砖magnesia carbon brick中性耐火材料neutral refractory material复合砖composite brick铝炭砖alumina carbon brick铝镁炭转alumina magnesia brick锆炭砖zirconia graphite brick镁钙炭砖magnesia clacia carbon brick长水口long nozzle浸入式水口immersion nozzle,submerged nozzle定径水口metering nozzle氧化铝-碳化硅-炭砖 Al2O3-SiC-C brick透气砖gas permeable brick,porous brick滑动水口slide gate nozzle水口砖nozzle brick塞头砖stopper绝热耐火材料insulating refractory轻质耐火材料light weight refractory袖砖sleeve brick格子砖checker brick,chequer brick陶瓷纤维ceramic fiber耐火纤维refractory fiber耐火浇注料refractory castable耐火混凝土refractory concrete荷重耐火性refractoriness under load抗渣性slagging resistance耐磨损性abrasion resistance5.3 碳素材料含碳元素材料 carbon materials无定形碳amorphous carbon金刚石diamond炭相学carbon micrography炭黑carbon black石油沥青petroleum pitch石油焦炭petroleum coke石墨化graphitization石墨化电阻炉electric resistance furnace for graphitization石墨纯净化处理purification treatment of graphite炭砖carbon brick炭块carbon block碳化硅基炭块SiC-based carbon block炭电极carbon electrode连续自焙电极Soderberg electrode石墨电极graphite electrode超高功率石墨电极ultra-high power graphite electrode石墨电极接头graphite electrode nipple石墨电极接头孔graphite electrode socket plug电极糊electrode paste石墨坩埚graphite crucible石墨电阻棒graphite rod resistor炭刷carbon brush高纯石墨high purity graphite5.4 铁合金铁合金ferroalloy硅铁ferrosilicon硅钙calcium silicon金属硅silicon metal锰铁ferromangnanese低碳锰铁low carbon ferromanganese硅锰silicomanganese金属锰manganese metal铬铁ferrochromium低碳铬铁low carbon ferrochromium微碳铬铁extra low carbon ferrochromium硅铬silicochromium金属铬chromium metal钨铁ferrotunsten钼铁ferromolybdenum钛铁ferrotitanium硼铁ferroboron铌铁ferroniobium磷铁ferrophosphorus镍铁ferronickel锆铁ferrozirconium硅锆silicozirconium稀土硅铁rare earth ferrosilicon稀土镁硅铁rare earth ferrosilicomagnesium成核剂nucleater孕育剂incubater,inoculant球化剂nodulizer蠕化剂vermiculizer中间铁合金master alloy复合铁合金complex ferroalloy电碳热法electro-carbothermic process电硅热法electro-silicothermic process铝热法aluminothermic process,thermit process电铝热法electro-aluminothermic process开弧炉open arc furnace埋弧炉submerged arc furnace半封闭炉semiclosed furnace封闭炉closed furnace矮烟罩电炉electric furnace with low hood矮炉身电炉low-shaft electric furnace5.5 烧结与球团人造块矿ore agglomerates烧结矿sinter压块矿briquette球团矿 pellet针铁矿goethite自熔性铁矿self-fluxed iron ore复合铁矿complex iron ore块矿lump ore粉矿ore fines矿石混匀ore blending配矿ore proportioning矿石整粒ore size grading返矿return fines储矿场ore stockyard矿石堆料机ore stocker匀矿取料机ore reclaimer熔剂flux消石灰slaked lime活性石灰quickened lime有机粘结剂organic binder烧结混合料sinter mixture烧结铺底料hearth layer for sinter烧结sintering烧结热前沿heat front in sintering烧结火焰前沿flame front in sintering渣相粘结slag bonding扩散粘结diffusion bonding带式烧结机Dwight-Lloyd sintering machine环式烧结机circular travelling sintering machine烧结梭式布料机shuttle conveyer belt烧结点火料sintering ignition furnace烧结盘sintering pan烧结锅sintering pot烧结冷却机sinter cooler带式冷却机straight-line cooler环式冷却机circular cooler,annular cooler生球green pellet,ball生球长大聚合机理ball growth by coalescence生球长大成层机理ball growth by layering生球长大同化机理ball growth by assimilation精矿成球指数balling index for iron ore concentrates生球转鼓强度drum strength of green pellet生球落下强度shatter strength of green pellet生球抗压强度compression strength of green pellet生球爆裂温度cracking temperature of green pellet圆筒造球机balling drum圆盘造球机balling disc竖炉陪烧球团shaft furnace for pellet firing带式机陪烧球团traveling grate for pellet firing链算机-回转窑陪烧球团grate-kiln for pellet firing环式机陪烧球团circular gates for pellet firing冷固结球团cold bound pellet维式体wustite铁橄榄石fayalite铁尖晶石hercynite铁黄长石ferrogehlenite铁酸半钙calcium diferrite铁酸钙calcium ferrite铁酸二钙dicalcium ferrite锰铁橄榄石knebelite钙铁橄榄石kirschsteinite钙铁辉石hedenbergite钙铁榴石andradite钙长石anorthite钙镁橄榄石monticellite钙钛矿perovskite硅灰石wollastonite硅酸二钙dicalcium silicate硅酸三钙tricalcium silicate镁橄榄石forsterite镁黄长石akermanite镁蔷薇辉石manganolite钙铝黄长石gehlenite钛辉石titanaugite枪晶石cuspidine预还原球团pre-reduced pellet金属化球团metallized pellet转鼓试验drum test,tumbler test落下试验shatter test5.6 高炉炼铁炼铁iron making高炉炼铁法 blast furnace process高炉blast furnace鼓风炉blast furnace炉料charge, burden矿料ore charge焦料coke charge炉料提升charge hoisting小车上料charge hoisting by skip吊罐上料charge hoisting by bucket皮带上料charge hoisting by belt conveyer装料charging装料顺序charging sequence储料漏斗hopper双料钟式装料two-bells system charging无料钟装料bell-less charging布料器distributor炉内料线stock line in the furnace探料尺gauge rod利用系数utilization coefficient冶炼强度combustion intensity鼓风blast风压blast pressure风温blast temperature鼓风量blast volume鼓风湿度blast humidity全风量操作full blast慢风under blowing休风delay喷吹燃料fuel injection喷煤coal injection喷油oil injection富氧鼓风oxygen enriched blast,oxygen enrichment置换比replacement ratio喷射器injector热补偿thermal compensation焦比coke ratio,coke rate燃料比fuel ratio,fuel rate氧化带oxidizing zone风口循环区raceway蒸汽鼓风humidified blast混合喷吹mixed injection脱湿鼓风dehumidified blast炉内压差pressure drop in furnace煤气分布gas distribution煤气利用率gas utilization rate炉况furnace condition顺行smooth running焦炭负荷coke load,ore to coke ratio软熔带cohesive zone,softening zone渣比slag to iron ratio,slag ratio上部炉料调节burden conditioning下部鼓风调节blast conditioning高炉作业率operation rate of blast furnace休风率delay ratio高炉寿命blast furnace campaign悬料hanging崩料slip沟流channeling结瘤scaffolding炉缸冻结hearth freeze-up开炉blow on停炉blow off积铁salamander炉型profile,furnace lines炉喉throat炉身shaft,stack炉腰belly炉腹bosh炉缸hearth炉底 bottom炉腹角bosh angle炉身角stack angle有效容积effective volume工作容积working bolume铁口iron notch, slag notch渣口cinder notch, slag notch风口tuyere窥视孔peep hole风口水套tuyere cooler渣口水套slag notch cooler风口弯头tuyere stock热风围管bustle pipe堵渣机stopper泥炮mud gun,clay gun开铁口机iron notch drill铁水hot metal铁水罐iron ladle鱼雷车torpedo car主铁沟sow出铁沟casting house铁沟iron runner渣沟slag runner渣罐cinder ladle, slag ladle撇渣器skimmer冷却水箱cooling plate冷却壁cooling stave汽化冷却vaporization cooling热风炉hot blast stove燃烧室combustion chamber燃烧器burner热风阀hot blast valve烟道阀chimney valve冷风阀cold blast valve助燃风机burner blower切断阀burner shut-off valve旁通阀by-pass valve混风阀mixer selector valve送风期on blast of stove,on blast燃烧期on gas of stove, on gas换炉stove changing放散阀blow off valve内燃式热风炉Cowper stove外燃式燃烧炉outside combustion stove顶燃式热风炉top combustion stove炉顶放散阀bleeding valve放散管bleeder上升管gas uptake放风阀snorting valve均压阀equalizing valve高压调节阀septum valve炉顶高压elevated top pressure铸铁机pig-casting machine铸铁模pig mold冲天炉cupola水渣granulating slag水渣池granulating pit渣场slag disposal pit高炉煤气top gas,blast furnace gas高炉煤气回收topgas recovery,TGR非焦炭炼铁non-coke iron making直接还原炼铁法direct reduction iron making直接还原铁directly reduced iron,DRI竖炉直接炼铁direct reduction in shaft furnace流态化炼铁fluidized-bed iron making转底炉炼铁rotary hearth iron making米德雷克斯直接炼铁法Midrex processHYL直接炼铁法 HYL process克虏伯回转窑炼铁法 Krupp rotary kiln iron-making熔态还原smelting reduction铁溶法iron-bath process科雷克斯法COREX process生铁pig iron海绵铁sponge iron镜铁spiegel iron清铁法H-rion process
展开阅读全文