IMDG-IMO危险品海洋污染物的分类及安全处置介绍农药部分课件

单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,IMDG/IMO危险品/海洋污染物的分类及安全、紧急处置,(,农药部分,),A),危险品分类,1) 3类易燃液体,2) 4类易燃固体,3) 5类氧化物,4) 6类有毒化合物,5) 8类腐蚀品,6) 9类环境污染物,1）3类易燃品,定义：,包括液体、混合液体、有固体物质包含其中的溶液，悬浮液，但这些不包括那些含有其他危险类别的固体物质。其闪点：,3.1类：,低闪点液体。闭杯闪点35C,3.3类：高闪点液体。闭杯闪点23C61C（141F） c.c；初沸点35C,包装：,3.1类：1类包装（Packing group I），非常危险。如异丙胺,3.2类：2类包装（Packing group II），中等危险。如甲醇(12C)、,丁醇、甲苯(7C)、二甲苯(1723C),3.3类：3类包装（Packing group III），较小危险。如戊醇、己醇、,环己酮(3844C),2,）,4,类易燃固体,4.1,类：易燃固体、自反应固体,代表物质：铝粉、二硝基苯酚（等硝基化合物）、六亚甲基四胺，硫，磷,4.3,类：与水接触后，非常危险的物质。,代表物质：磷化锌、磷化镁、磷化铝，氰氨化钙等,3,）,5,类,氧化物,5.1,类：,硝酸铵,(,化肥,),、硝酸钾（硝酸盐）、次氯酸钙,(,漂白粉,),等,5.2,类：,有机过氧化物,农药中很少涉及,。化工品出口部分涉及。,6.1,类：有毒化合物,定义：有毒化合物的定义是以该产品的大鼠经口,(,或经皮，吸入。通常用经口判断就可以了,),的急性半致死中量（,LD,50,）来判断。,包装类别,经口急性,LD50,（,IMDG,）,I 5 mg/kg,。非常严重的中毒危险性。,该类的产品,很少,。,II 5 50 mg/kg,。严重的中毒危险性。,如：,Methomyl 90% SP,，,Carbofuran 48% SC,III,固体, 50 200 mg/kg,。低毒,液体, 50 500 mg/kg,。低毒,4,）,6,类,有毒化合物,即，理论上来说，固体货物大鼠经口,LD,50, 200 mg/kg,，液体货物大鼠经口,LD,50, 500 mg/kg,，就不归,6.1,。在没有其他危险性（如，非腐蚀性、非环境污染物等）的情况下，就可归入普货。但，在实际,危包证的出具中，并没有严格的遵循这个规则，很多,9,类的固体,/,粉剂产品也给出具了,6.1,类的危包。但，这个标准可以作为在无需出具危包证的半危出运中作为参考。,6.1,类产品比较多。,详见附件介绍！,6.2,类：,传染性物质,(,农药几无涉及,),对于农药品种来说，归入该类别的主要产品是乙烯利水剂 （,UN3265,）。,5,）,8,类,腐蚀品,UN3077,（,S,），,UN3082,（,L,）,对于农药产品来说，绝大多数的产品，若没有归入其他的类别，均可归入该类别中。,9,）,9,类,环境污染物,附：,6.1,类有毒化合物,UN No / IMDG code,概述：,如果在运输过程中需要提供,6.1,类货物的,IMDG code,，大部分的产品，只需要根据危包证上的,UN No,，在,IMDG,手册上查找，就可以找到对应的,IMDG code,。,在收到的危包证上，各个产品的,UN No,，留意会发现，有时不同的有效成分的号是一样的，而同样的有效成分的号反而会不一样。当然，不同的有效成分，,UN No,也有不一样的，等等情况。这涉及到产品的不同剂型，毒性，化学类别。,大类产品：,1.,有机磷农药,根据产品的剂型（液体，还是固体），及闪点（液体）的不同。有机磷农药的归入如下,UN No,：,2783:,ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC,可湿性粉剂、可溶性粉机、颗粒剂、固体原药等,2784:,ORGANOPHOSPHORUS PESTICIDE, LIQUID,FLAMMABLE, TOXIC, flash point less than 23 C,液体,(,一般是乳油,),，闪点低于,23C c.c.,3017,:ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC,FLAMMABLE, flash point not less than 23 C,液体,(,一般是乳油,),，闪点大于,23C c.c.,，小于,61C c.c.,3018,:ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC,液体,(,一般是乳油,液体农药,),，闪点高于,61C c.c.,有机磷农药产品列表：,根据产品的剂型（液体，还是固体），及闪点（液体）的不同。氨基甲酸酯农药归入如下,UN No,：,2757,:CARBAMATE PESTICIDE, SOLID, TOXIC,可湿性粉剂、可溶性粉机、颗粒剂、固体原药等,2758:,CARBAMATE PESTICIDE, LIQUID, FLAMMABLE,TOXIC, flash point less than 23 C,液体,(,一般是乳油,),，闪点低于,23C c.c.,2991,:CARBAMATE PESTICIDE, LIQUID, TOXIC,FLAMMABLE, flash point not less than 23 C,液体,(,一般是乳油,),，闪点大于,23C c.c.,，小于,61C c.c.,2992:,CARBAMATE PESTICIDE, LIQUID, TOXIC,液体,(,一般是乳油，液体农药,),，闪点高于,61C c.c.,2.,氨基甲酸酯,农药,氨基甲酸酯,农药产品列表：,根据产品的剂型（液体，还是固体），及闪点（液体）的不同。拟除虫菊酯农药归入如下,UN No,：,3349,:PYRETHROID PESTICIDE, SOLID, TOXIC,可湿性粉剂、可溶性粉机、颗粒剂、固体原药等,3350:,PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC,flash point less than 23 C,液体,(,一般是乳油,),，闪点低于,23C c.c.,3351,:PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE,flash point not less than 23 C,液体,(,一般是乳油,),，闪点大于,23C c.c.,，小于,61C c.c.,3352:,PYRETHROID PESTICIDE, LIQUID, TOXIC,液体,(,一般是乳油，液体农药,),，闪点高于,61C c.c.,3.,拟除虫菊酯,拟除虫菊酯,农药产品列表：,根据产品的剂型（液体，还是固体），及闪点（液体）的不同。香豆素衍生物农药归入如下,UN No,：,3024,:COUMARIN DERIVATIVE PESTICIDE, LIQUID,FLAMMABLE, TOXIC, flash point less than 23 C,3025:,COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC,FLAMMABLE, flash point not less than 23 C,液体,(,一般是母液,),，闪点,不低于,23C c.c.,3026,:COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC,液体,(,一般是母液,),，闪点高于,61C c.c.,3027:COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC,饵剂、固体原药等,4.,香豆素衍生物,香豆素衍生物,农药产品列表：,中文名称,英文名称,1,溴鼠灵,Brodifacoum,2,溴敌隆,Bromadiolone,3,杀鼠醚,Coumatetralyl,4,氟鼠灵,Flocoumafen,5,杀鼠灵,Warfarin,根据产品的剂型（液体，还是固体），及闪点（液体）的不同。有机氯农药归入如下,UN No,：,2761,:ORGANOCHLORINE PESTICIDE, SOLID, TOXIC,2762:,ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE,TOXIC, flash point less than 23 C,2995,:ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC,FLAMMABLE, Flash point not less than 23 C,2996:,ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC,5.,有机氯农药,背景小知识及产品：,背景小知识：,有机氯农药是农药发展史上最为重要的一类化合物，其代表产品为六六六，,DDT,。而,DDT,因其在健康方面的贡献,(,杀除蚊虫，控制疟疾,),，其发明人与,1948,年获得了诺贝尔生理,/,医学奖。在二战期间，因,DDT,的使用，挽救了成千上万的性命。,DDT,后来因发现其不易降解，在生物体内的富集，从而对人和环境生物造成更为严重要的危害而被禁用。若不考虑累计毒性的话，到目前为止，还没有找到其他能够与之匹敌的产品：可以在人或人类生活环境中随意使用，而不会造成中毒，但却能够有效的杀灭蚊虫，从而取得良好的卫生防疫效果。,由于残留严重，,目前,市场上的,有机氯产品剩下,已经不多,了,。,产品：,三氯杀螨醇,/dicofol,、硫丹,/endosulfan,、三氯杀螨砜,/tetradifon,根据产品的剂型（液体，还是固体），及闪点（液体）的不同。有机锡农药归入如下,UN No,：,2786,:ORGANOTIN PESTICIDE, SOLID, TOXIC,2787:,ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC,flash point less than 23 C,3019,:ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE,Flash point not less than 23 C,3020:,ORGANOTIN PESTICIDE, LIQUID, TOXIC,实际产品中，只有,UN2786,（,WP,）、,UN3020,（,SC,）,6.,有机锡农药,有机锡,农药产品列表：,中文名称,英文名称,1,三唑锡,Azocyclotin,2,三环锡,Cyhexatin,3,苯丁锡,Fenbutatin Oxide,4,三苯基氢氧化锡,三苯基氢醋酸锡,Fentin hydroxide,Fentin Acetate,5,三磷锡,Phostin,根据产品的剂型（液体，还是固体），及闪点（液体）的不同。未归类,6.1,农药如下,UN No,：,2588:,PESTICIDE, SOLID, TOXIC, N.O.S.,2902:,PESTICIDE, LIQUID, TOXIC, N.O.S.,2903,:PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S.,Flash point not less than 23 C,3021,:PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S.,Flash point less than 23 ,7.,其他未归类,6.1,农药,复配产品,烟碱类产品，如吡虫啉、啶虫脒等,其他产品，如氟虫腈、虫螨腈、多杀菌素、阿维菌素、甲氨基阿维菌素、茚虫威等,未归类,6.1,农药产品列表：,B,),EMS NO.,EMS,Emergency Schedules,危险品应急措施,代码,总论,EMS,（,危险品应急措施,），着重关注两个应急措施的方面：,1,）火险情况下的紧急应对。即，,IMO,应对措施“,F -,？”中的“,F,”,2,）泄露情况下的紧急应对。即，,IMO,应对措施“,S -,？”中的“,S,”,Emergency Schedules for Fire,EMS code for fire as below:,F A:GENERAL FIRE SCHEDULE,F B:EXPLOSIVE SUBSTANCES AND ARTICLES,F C:NON-FLAMMABLE GASES,F D:FLAMMABLE GASES,F E:NON-WATER REACTIVE FLAMMABLE LIQUIDS,F F:TEMPERATURE CONTROLLED SELF-REACTIVES AND,ORGANIC PEROXIDES,F G:WATER REACTIVE SUBSTANCES,F H:OXIDIZING SUBSTANCES WITH EXPLOSIVE POTENTIAL,F I:RADIOACTIVE MATERIAL,F J:NON-TEMPERATURE CONTROLLED SELF-REACTIVES,AND ORGANIC PEROXIDES,从对,F A,到,F J,的适用对象定义，可以看出，农药产品适用的代码,/Code,为“,F A,”和“,F E,”。,F A:,水剂、悬浮剂、固体、高闪点液体农药：,如,2588,、,2902,F E:,乳油等含低闪点溶剂,易燃,农药：,如,2903,、,3021,、,1993,Emergency Schedules for Spillage,S A:TOXIC SUBSTANCES,S B: CORROSIVE SUBSTANCES,S C: FLAMMABLE, CORROSIVE LIQUIDS,S D: FLAMMABLE LIQUIDS,S E: FLAMMABLE LIQUIDS, FLOATING ON WATER,S F: WATER SOLUBLE MARINE POLLUTANTS,S G: FLAMMABLE SOLIDS AND SELF-REACTIVE SUBSTANCES,S H:FLAMMABLE SOLIDS (MOLTEN MATERIAL),S I:FLAMMABLE SOLIDS (REPACKING POSSIBLE),S J:WETTED EXPLOSIVES AND CERTAIN SELF-HEATING,SUBSTANCES,S K:TEMPERATURE-CONTROLLED SELF-REACTIVE,SUBSTANCES,S L:SPONTANEOUSLY COMBUSTIBLE, WATER-REACTIVE,MATERIAL,S M:HAZARD OF SPONTANEOUS IGNITION,EMS code for spillage as below:,S N:SUBSTANCES REACTING VIGOROUSLY WITH WATER,S O:SUBSTANCES DANGEROUS WHEN WET (NON-,COLLECTABLE ARTICLES),S P:SUBSTANCES DANGEROUS WHEN WET (COLLECTABLE,ARTICLES),S Q:OXIDIZING SUBSTANCES,S R:ORGANIC PEROXIDES,S S:RADIOACTIVE MATERIAL,S T:DANGEROUS GOODS WITH BIOHAZARD,S U:GASES (FLAMMABLE, TOXIC OR CORROSIVE),S V:GASES (NON-FLAMMABLE, NON-TOXIC),S W:OXIDIZING GASES,S X:EXPLOSIVE ITEMS AND ARTICLES,S Y:EXPLOSIVE CHEMICALS,S Z:TOXIC EXPLOSIVES,从对,S A,到,S Z,的适用对象定义，可以看出，农药产品适用的代码,/Code,为,:,S A, S B, S D, S E, S ,F,S A,：,6.1,类的水剂、悬浮剂、固体、高闪点液体农药。如,UN2588,、,2902,、,2783,、,3018,、,2757,、,2992,等,S B,：乙烯利水剂，,UN3265,。,S D,：易,/,可燃液体农药：如,UN2903,、,3021,、,2784,、,3017,、,2758,、,2991,等,S E,：,UN1993,S F,：,UN3077,、,3082,EMS code for Fire,F A,、,F E,F A:GENERAL FIRE SCHEDULE,F E:NON-WATER REACTIVE FLAMMABLE LIQUIDS,Conclusion on EMS code for fire and spillage,EMS code for Spillage,S A,、,S B,、,S D,、,S E,、,S ,F,S A:TOXIC SUBSTANCES,S B: CORROSIVE SUBSTANCES,S D: FLAMMABLE LIQUIDS,S E: FLAMMABLE LIQUIDS, FLOATING ON WATER,S F: WATER SOLUBLE MARINE POLLUTANTS,Conclusion on EMS code for fire and spillage,其他,危险品货物描述、顺序及其他信息,UN Number,Proper Shipping Name, technical name (if have),IMO Class (sub risk),Packing Group,Flash point (if have),Marine pollutant (if have),Package quantity (please remarks, if have inter package),1,、,The UN number (,联合国编码,),：例如，联合国编码是,2588,，请填写为,UN2588,；,2,、,Proper Shipping Name (,危险货物正确学名,),如果该货物有,Technical name (,Imidacloprid 70% WG,),请填写,Technical name,一栏，以下是范例,:,PESTICIDE, SOLID, TOXIC, N.O.S. (Imidacloprid),Proper shipping name Technical name,3,、,IMO Class (,危险货物等级,),：例如，危险等级是,6.1,，请填写为,Class 6.1.,；如果该类危险品有附 危险等级，请填在主危险等级后面，例如：,5.1(3),。,4,、,Packing group (,包装类别,),：如果该危险品货物有包装类别,请提供包装类别并在前加,PG,； 例如，包装类别是,III,，请填写为,PG III,。,Packing group,分为三种：,I, II, III.,如果没有包装类别，无需提供包装,5,、,Flash Point (,闪点,):,如果该危险品货物有闪点，请提供闪点。,6,、,Marine Pollutant (,海洋污染,):,有,N, P, PP,三种类别。,N,：无污染的物质,P:,有污染性的物质,PP:,有严重污染性的物质,其他,常见农药产品危险性描述及其,Ems,GLYPHOSATE,UN Number,3077,Proper Shipping Name,Environmentally Hazardous Substance, Solid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,Glyphosate TC and SG:,UN Number,3082,Proper Shipping Name,Environmentally Hazardous Substance, Liquid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,Glyphosate SL,2,4-D & ITS ESTER,UN Number,3345,3077,Proper Shipping Name,Phenoxyacetic Acid Derivative Pesticide, Solid, Toxic,Environmentally Hazardous,Substance, Solid, N.O.S.,IMO Class,6.1,9,Packing Group,III,III,Ems Code,F-A S-A,F-A S-F,2,4-D (acid & salt) TC & SP formulation,UN Number,3082,Proper Shipping Name,Environmentally Hazardous Substance, Liquid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,2,4-D salt SL, 2,4-D ester TC, 2,4-D ester EC (F.p. 61,),UN Number,1993,Proper Shipping Name,Flammable Liquid, N.O.S.,IMO Class,3,Packing Group,I III,Ems Code,F-E S-E,2,4-D ester EC (F.p. 61,),Dicamba, MCPA, Picloram, Triclopyr,产品危险性分类，除没有,UN3345,的类别外，其他同,2,4-D,产品系列！,PARAQUAT DICHLORIDE DIQUAT DIBROMIDE,UN Number,3016,Proper Shipping Name,Bipyridilium Pesticide, Liquid, Toxic,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,TK and SL,FIPRONIL,UN Number,2588,Proper Shipping Name,Pesticide, Solid, Toxic, N.O.S.,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,UN Number,2902,Proper Shipping Name,Pesticide, Liquid, Toxic, N.O.S.,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,Technical material and WDG formulation,SC formulation,ETHEPHON,UN Number,3265,Proper Shipping Name,8,IMO Class,III,Packing Group,CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.,Ems Code,F-A S-B,Ethephon TC and SL,IMIDACLOPRID, ACETAMIPRID, THIAMETHOXAM, NITENPYRAM, THIACLOPRID,UN Number,2588,Proper Shipping Name,Pesticide, Solid, Toxic, N.O.S.,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,Technical material and WP, SP, WG, GR, WS formulation,UN Number,2902,Proper Shipping Name,Pesticide, Liquid, Toxic, N.O.S.,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,SL, SC formulation,CARTAP HYDROCHLORIDE,UN Number,2771,Proper Shipping Name,Thiocarbamate Pesticide, Solid, Toxic,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,UN Number,3077,Proper Shipping Name,Environmentally Hazardous Substance, Solid, N.O.S.,.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,UN Number,2588,Proper Shipping Name,Pesticide, Solid, Toxic, n.o.s.,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,由于产品的化学分类不明确，及急性毒数据介于低毒,中等毒。这个产品原药、,SP,的归类比较乱。所列的,3,个,UN NO.,均可用。,4% GR,原则上应该是,UN3077,。但，实际操作时，也有可能被归入,6.1,的,UN NO.,中！,Cartap Hydrochloride TC and SP formulation,Cartap Hydrochloride 4% GR,UN Number,3077,Proper Shipping Name,Environmentally Hazardous Substance, Solid, N.O.S.,.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,ABAMECTIN, EMAMECTIN,UN Number,2588,Proper Shipping Name,Pesticide, Solid, Toxic, N.O.S.,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,Technical material and WP, SG formulation,UN Number,2902,Proper Shipping Name,Pesticide, Liquid, Toxic, N.O.S.,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,EC formulation,UN Number,2903,3021,Proper Shipping Name,Pesticide, Liquid, Toxic, Flammable, N.O.S.,(F.p.: not less than 23 C),Pesticide, Liquid, Toxic, Flammable, N.O.S.,(F.p.: less than 23 C),IMO Class,6.1 (3),3 (6.1),Packing Group,III,III,Ems Code,F-E S-D,F-E S-D,ACETOCHLOR, ALACHLOR, BUTACHLOR, METOLACHLOR, PRETILACHLOR,UN Number,3082,Proper Shipping Name,Environmentally Hazardous Substance, Liquid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,Technical Material,UN Number,3082,Proper Shipping Name,Environmentally Hazardous Substance, Liquid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,UN Number,1993,Proper Shipping Name,Flammable Liquid, N.O.S,. (F.p. 61,),IMO Class,3,Packing Group,III,Ems Code,F-E S-E,EC Formulation,ATRAZINE, AMETRYNE, CYANAZINE, HEXAZINONE, METRIBUZIN, PROMETRYN, PROPAZINE, SIMAZINE, SIMETRYN, TERBUTHYLAZINE, TERBUTRYN,UN Number,3077,Proper Shipping Name,Environmentally Hazardous Substance, solid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,Technical Material and WP, WG formulation,UN Number,3082,Proper Shipping Name,Environmentally Hazardous Substance, Liquid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,SC Formulation,CYPROCONAZOLE, DIFENOCONAZOLE, DINICONAZOLE(-M), FENBUCONAZOLE, FLUSILAZOLE, FLUTRIAFOL, HEXACONAZOLE, MYCLOBUTANIL, PACLOBUTRAZOL, PROPICONAZOLE, TEBUCONAZOLE, TRIADIMEFON, TRIADIMENOL, TRICYCLZOLE, TRITICONAZOLE, UNICONAZOLE,UN Number,3077,Proper Shipping Name,Environmentally Hazardous Substance, solid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,Technical Material (Solid) and WP, WG, WS formulation,UN Number,3082,Proper Shipping Name,Environmentally Hazardous Substance, Liquid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,SC, FS Formulation,UN Number,3082,1993,Proper Shipping Name,Environmentally Hazardous Substance, Liquid, N.O.S.,Flammable Liquid, N.O.S,.,(F.p. 61,),IMO Class,9,3,Packing Group,III,III,Ems Code,F-A S-F,F-E S-E,EC Formulation,AZOXYSTROBIN, KRESOXIM-METHYL, TRIFLOXYSTROBIN, PYRACLOSTROBIN,UN Number,3077,Proper Shipping Name,Environmentally Hazardous Substance, solid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,Technical Material and WG, WS formulation,UN Number,3082,Proper Shipping Name,Environmentally Hazardous Substance, Liquid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,SC, FS Formulation,DICLOFOP-METHYL, FENOXAPROP-P-ETHYL, FLUAZIFOP-P-BUTYL, HALOXYFOP-R-METHYL, QUIZALOFOP-P-ETHYL, CYHALOFOP-BUTYL, QUIZALOFOP-P-TEFURYL, CLODINAFOP-PROPARGYL,UN Number,3077,Proper Shipping Name,Environmentally Hazardous Substance, solid, N.O.S.,IMO Class,9,Packing Group,III,Ems Code,F-A S-F,Technical Material,UN Number,3082,1993,Proper Shipping Name,Environmentally Hazardous Substance, Liquid, N.O.S.,Flammable Liquid, N.O.S,.,(F.p. 61,LIQUID FORMULATION*,EC FORMULATION,UN Number,3017,2784,Proper Shipping Name,Organophosphorus Pesticide, Liquid, Toxic, Flammable,(F.p. Not less than 23,C),Organophosphorus Pesticide, Liquid, Flammable, Toxic,(F.p.: Less,than 23 C),IMO Class,6.1 (3),3 (6.1),Packing Group,III,III,Ems Code,F-E S-D,F-E S-D,UN Number,2783,Proper Shipping Name,Organophosphorus Pesticide, Solid, Toxic,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,WP, SP, GR FORMULATION,LIQUID:,Benfuracarb, Fenobucarb, Carbosulfan,SOLID:,Carbaryl, Carbofuran, Isoprocarb, Methomyl, Propoxur, Thiodicarb,CARBAMATE PESTICIDE,氨基甲酸酯农药,UN Number,2992,2757,Proper Shipping Name,Carbamate Pesticide, Liquid, Toxic,Carbamate Pesticide, Solid, Toxic,IMO Class,6.1,6.1,Packing Group,III,III*,Ems Code,F-A S-A,F-A S-A,TECHNICAL MATERIAL,*) Carbofuran & Methomyl:,Packing group II,UN Number,2992,Proper Shipping Name,Carbamate Pesticide, Liquid, Toxic,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,LIQUID FORMULATION*,*) Including EC, SC, EW,formulation (if any),F.p. 61,UN Number,2758,2991,Proper Shipping Name,Carbamate Pesticide, Liquid, Flammable, Toxic,(F.p.: Less,than 23 C),Carbamate Pesticide, Liquid, Flammable, Toxic,(F.p.: Not,less than 23 C),IMO Class,3 (6.1),6.1(3),Packing Group,III,III,Ems Code,F-E S-D,F-E S-D,EC FORMULATION,UN Number,2757,Proper Shipping Name,Carbamate Pesticide, Solid, Toxic,IMO Class,6.1,Packing Group,III,*,Ems Code,F-A S-A,*) Methomyl SP/WP:,Packing group II,WP, WDG/DF, SP, GR FORMULATION,LIQUID:,Bioallethrin, Cypermethrin, Cyfluthrin, D-allethrin, D-phenothrin, Esbiothrin, Fenpropathrin,Fenvalerate, Esfenvalerate, Permethrin,SOLID:,Alpha-cypermethrin, Beta-cyfluthrin, Beta-cypermethrin, Bifenthrin, Deltamethrin, Etofenprox,Lambda-cyhalothrin, Tetremethrin,PYRETHROID PESTICIDE,拟除虫菊酯农药,UN Number,3352,3349,Proper Shipping Name,Pyrethroid Pesticide, Liquid, Toxic,Pyrethroid Pesticide, Solid, Toxic,IMO Class,6.1,6.1,Packing Group,III,III,Ems Code,F-A S-A,F-A S-A,TECHNICAL MATERIAL,UN Number,3352,Proper Shipping Name,Pyrethroid Pesticide, Liquid, Toxic,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,*) Including EC, SC, EW,formulation (if any).,F.p. 61,LIQUID FORMULATION*,UN Number,3350,3351,Proper Shipping Name,Pyrethroid Pesticide, Liquid, Flammable, Toxic,(F.p.: Less,than 23 C),Pyrethroid Pesticide, Liquid, Flammable, Toxic,(F.p.: Not,less than 23 C),IMO Class,3 (6.1),6.1 (3),Packing Group,III,III,Ems Code,F-E S-D,F-E S-D,EC FORMULATION,UN Number,3349,Proper Shipping Name,Pyrethroid Pesticide, Solid, Toxic,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,WP, WDG/DF, GR FORMULATION,Coumatetralyl/,杀鼠醚、,Brodifacoum/,溴鼠灵、,Bromadiolone/,溴敌隆、,Warfarin/,杀鼠灵,杀鼠剂,/ Rodenticide (,香豆素类,),UN Number,3027,Proper Shipping Name,Coumarin Derivative Pesticide, Solid, Toxic,IMO Class,6.1,Packing Group,II,Ems Code,F-A S-A,TECHNICAL MATERIAL:,UN Number,3027,3025,Proper Shipping Name,Coumarin Derivative Pesticide, Solid, Toxic,Coumarin Derivative Pesticide, Solid, Toxic,IMO Class,6.1,6.1,Packing Group,III,III,Ems Code,F-A S-A,F-A S-A,TECHNICAL CONCENTRATE,UN Number,3027,Proper Shipping Name,Coumarin Derivative Pesticide, Solid, Toxic,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,BLOCK BAIT*,*),因饵剂的含量很低,(,主流含量,0.005%),，该产品的急性毒性很低，可归入普货。,题外：,Warfarin,是一种治疗心脏病的药物，用于预防血管栓塞,Dicofol /,三氯杀螨醇、,Endosulfan /,硫丹、,Tetradifon /,三氯杀螨砜,ORGANOCHLORINE PESTICIDE /,有机氯农药,UN Number,2996,Proper Shipping Name,Organochlorine Pesticide, Liquid, Toxic,IMO Class,6.1,Packing Group,III,Ems Code,F-A S-A,TECHNICAL MATERIAL:,UN Number,2762,2995,Proper Shipping Name,Organochlorine Pesticide, Liquid, Flammable, Toxic,(F.p.: Less,than 23 C),Organochlorine Pesticide, Liquid, Flammable, Toxic,(F.p.: Not,less than 23 C),IMO Class,3 (6.1),6.1 (3),Packing Group,III,III,Ems Code,F-E S-D,F-E S-D,EC FORMULATION:,Fentin Acetate, Fentin Hydroxide, Fenbutatin oxide, Cyhex